Vanadium procatalysts bearing chelating aryloxides: structure–activity trends in ethylene polymerisation

C Redshaw - Dalton Transactions, 2010 - pubs.rsc.org
High-valent vanadium complexes bearing a variety of chelating aryloxides including di-and
linear tri-phenolates, C/N-capped tripods, phenoxyimines and calixarenes type ligands …

Benzene selectivity in competitive arene hydrogenation: effects of single-site catalyst··· acidic oxide surface binding geometry

W Gu, MM Stalzer, CP Nicholas… - Journal of the …, 2015 - ACS Publications
Organozirconium complexes are chemisorbed on Brønsted acidic sulfated ZrO2 (ZrS),
sulfated Al2O3 (AlS), and ZrO2–WO3 (ZrW). Under mild conditions (25° C, 1 atm H2), the …

P, O-Phosphinophenolate zinc (II) species: synthesis, structure and use in the ring-opening polymerization (ROP) of lactide, ε-caprolactone and trimethylene …

C Fliedel, V Rosa, FM Alves, AM Martins, T Avilés… - Dalton …, 2015 - pubs.rsc.org
The P, O-type phosphinophenol proligands (1· H, 2-PPh2-4-Me-6-Me-C6H2OH; 2· H, 2-
PPh2-4-Me-6-tBu-C6H2OH) readily react with one equiv. of ZnEt2 to afford in high yields the …

Synthesis and Structure of Neutral and Cationic Aluminum Complexes Supported by Bidentate O,P-Phosphinophenolate Ligands and Their Reactivity with …

M Haddad, M Laghzaoui, R Welter, S Dagorne - Organometallics, 2009 - ACS Publications
The O, P-type phosphinophenol ligands 1a− c were found to readily react with 1 equiv of
AlMe3 to afford in high yields the corresponding Al chelate complexes {η2-O, P-(2-PPh2-4 …

Gas-phase loading of [Zn 4 O (btb) 2](MOF-177) with organometallic CVD-precursors: inclusion compounds of the type [L n M] a@ MOF-177 and the formation of Cu …

M Müller, OI Lebedev, RA Fischer - Journal of Materials Chemistry, 2008 - pubs.rsc.org
The highly porous and desolvated (activated) coordination polymer [Zn4O (btb) 2](btb=
benzene-1, 3, 5-tribenzoate; MOF-177) was loaded with the organometallic compounds …

Dithiodiolate ligands: group 4 complexes and application in lactide polymerization

E Sergeeva, J Kopilov, I Goldberg, M Kol - Inorganic chemistry, 2010 - ACS Publications
Dithiodiolate ligands were synthesized by reacting 1, 2-ethanedithiol or 1, 2-benzenedithiol
with 2, 2-bis (trifluoromethyl) oxirane, led selectively to mononuclear octahedral group 4 …

Group 4 metal olefin polymerization catalysts stabilized by bidentate O, P ligands

RJ Long, VC Gibson, AJP White - Organometallics, 2008 - ACS Publications
A series of bis (phosphanylphenoxide) group 4 metal dichloride complexes has been
synthesized via treatment of MCl4 (THF) 2 (M= Ti, Zr, Hf) with sodium salts of the …

Addition of C–H bonds of pyridine derivatives to alkenes catalyzed by zirconium complexes bearing amine-bridged bis (phenolato) ligands

Q Sun, P Chen, Y Wang, Y Luo, D Yuan… - Inorganic …, 2018 - ACS Publications
Cationic zirconium complexes in situ generated from zirconium dibenzyl complexes bearing
amine-bridged bis (phenolato) ligands have been developed to catalyze addition of C (sp2) …

Novel titanium (IV) diolate complexes with thiophene-containing OSO-type ligand as pre-catalyst for ethylene polymerization and ethylene-propylene copolymerization

VA Tuskaev, SC Gagieva, AV Churakov… - Journal of …, 2022 - Elsevier
New titanium (IV) complexes with diolate ligand containing additional donor sulfur atom
have been synthesized and characterized. Structure of complex 2 was established by X-ray …

Multidentate fluorinated alkoxide ligand platforms for oxophilic metal centers: from MOCVD source reagents to polymerization catalysts

JF Carpentier - Dalton Transactions, 2010 - pubs.rsc.org
In contrast to simple fluorinated alkoxides, the coordination chemistry of multidentate ligands
that incorporate OC (CF3) 2CR2-type moieties and additional donors (N, O, etc.) has been …