Deoxy sugars represent an important class of carbohydrates, present in a large number of
biomolecules involved in multiple biological processes. In various antibiotics, antimicrobials …

Recent advances in synthetic methods and monomer design have given access to precision
carbohydrate polymers that extend beyond native polysaccharides. In this article, we present …

Stereoselective β-mannosylation is one of the most challenging problems in the synthesis of
oligosaccharides. Herein, a highly selective synthesis of β-mannosides and β-rhamnosides …

Controlling the stereoselectivity of 1, 2-cis glycosylation is one of the most challenging tasks
in the chemical synthesis of glycans. There are various 1, 2-cis glycosides in nature, such as …

Boronic acid-catalyzed regioselective Koenigs–Knorr-type glycosylation is presented. The
reaction of an unprotected or partially protected glycosyl acceptor with a glycosyl halide …

Synthesis of an antigenic tetrasaccharide repeating unit of the O-polysaccharide of
Salmonella enteritidis lipopolysaccharide has been accomplished. Those four …

A direct, efficient, and versatile glycosylation methodology promises the systematic synthesis
of oligosaccharides and glycoconjugates in a streamlined fashion like the synthesis of …

Cesium carbonate promoted direct amidation of unactivated esters with amino alcohols was
developed without the use of transition-metal catalysts and coupling reagents. This method …

Stereoselective synthesis of d-glycero-and l-glycero-β-d-mannoheptosides has been
achieved by cesium carbonate-mediated β-selective anomeric O-alkylation of the …

Recent efforts in the field of carbohydrate chemistry have focused on the site-and
stereocontrolled synthesis of O-glycosides derived from acceptors bearing multiple hydroxyl …