Organic halides are very important and versatile compounds with many applications as
starting materials, solvents, reagents, and intermediates in synthetic organic chemistry. 1 …

Understanding the energy it takes to build or break chemical bonds is essential for scientists
and engineers in a wide range of innovative fields, including catalysis, nanomaterials …

This short review deals with reports published in the last 2 years concerning catalytic,
mechanistic, synthetic and stuctural aspects of hydrosilylation as well as asymmetric …

A large number of papers dealing with silyl radi-cals, dating back to thelate 1940s, has been
pub-lished. Initially, silicon-centered radicals were pos-tulated as intermediates in the …

The enthalpy change that occurs in a photoinduced chemical reaction in solution can be
quantified by a relatively simple technique known as photoacoustic calorimetry (PAC), which …

Reagents, containing a PH bond, such as dimethyl phosphite, diethyl phosphite,
hypophosphorous acid and various salts of hypophosphorous acid are effective radical …

A new strategy has been developed for reductive amination of aldehydes and ketones with
the InCl3/Et3SiH/MeOH system, which is a nontoxic system with highly chemoselective and …

Publisher Summary Collection of kinetic data for reactions of the group 14 hydrides with
various radicals provides essential information to chemists in both the synthetic and physical …

A radical initiator-free defunctionalization reaction of alkyl isocyanides with a hydrosilane
has been established through C–N bond cleavage under catalyst-free visible light …

Deoxygenations of alcohols, ie, processes that replace a hydroxyl group with hydrogen at a
saturated carbon, find applications in both total synthesis and the systematic modifications of …