Solution behaviors and self-assembly of polyoxometalates as models of macroions and amphiphilic polyoxometalate–organic hybrids as novel surfactants
Large, hydrophilic polyoxoanions with high solubility in water and/or other polar solvents
demonstrate unique solution behavior by self-assembling into single layer, hollow, spherical …
demonstrate unique solution behavior by self-assembling into single layer, hollow, spherical …
From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry
A Müller, P Gouzerh - Chemical Society Reviews, 2012 - pubs.rsc.org
Following Nature's lessons, today chemists can cross the boundary of the small molecule
world to construct multifunctional and highly complex molecular nano-objects up to protein …
world to construct multifunctional and highly complex molecular nano-objects up to protein …
Polyoxometalates-functionalized electrodes for (photo) electrocatalytic applications: Recent advances and prospects
This review is intended to provide an up-to-date and comprehensive description of recent
advances since the mid-2010s in the elaboration and the involvement of polyoxometalates …
advances since the mid-2010s in the elaboration and the involvement of polyoxometalates …
Self-assembly in aqueous solution of wheel-shaped Mo154 oxide clusters into vesicles
Surfactants and membrane lipids readily assemble into complex structures such as micelles,
liposomes or hollow vesicles owing to their amphiphilic character—the fact that part of their …
liposomes or hollow vesicles owing to their amphiphilic character—the fact that part of their …
Archimedean synthesis and magic numbers:“sizing” giant molybdenum‐oxide‐based molecular spheres of the keplerate type
Pythagorean harmony can be found in the spherical polyoxometalate clusters described
here (see illustration for an example of a structure), since there are interesting relationships …
here (see illustration for an example of a structure), since there are interesting relationships …
Soluble molybdenum blues “des pudels kern”
A Müller, C Serain - Accounts of chemical research, 2000 - ACS Publications
The earlier tremendous interest in molybdenum blue solutions an enigma for generations of
chemists became even more pronounced when it turned out that the basic building units …
chemists became even more pronounced when it turned out that the basic building units …
An integrated giant polyoxometalate complex for photothermally enhanced catalytic oxidation
X Chen, G Zhang, B Li, L Wu - Science Advances, 2021 - science.org
A strategy integrating near infrared (NIR) photothermal and catalytic effects within one active
center beyond ultraviolet and visible light is proposed without the combination of separated …
center beyond ultraviolet and visible light is proposed without the combination of separated …
Unveiling the transient template in the self-assembly of a molecular oxide nanowheel
Self-assembly has proven a powerful means of preparing structurally intricate
nanomaterials, but the mechanism is often masked by the common one-pot mixing …
nanomaterials, but the mechanism is often masked by the common one-pot mixing …
Toward nanodevices: synthesis and characterization of the nanoporous surfactant-encapsulated keplerate (DODA) 40 (NH4) 2 [(H2O) n⊂ Mo132O372 (CH3COO) 30 …
We describe the spontaneous self-assembly and the superstructure of a discrete surfactant-
encapsulated cluster,(DODA) 40 (NH4) 2 [(H2O) n⊂ Mo132O372 (CH3COO) 30 (H2O) …
encapsulated cluster,(DODA) 40 (NH4) 2 [(H2O) n⊂ Mo132O372 (CH3COO) 30 (H2O) …
The Construction of High‐Nuclearity Isopolyoxoniobates with Pentagonal Building Blocks: [HNb27O76]16− and [H10Nb31O93(CO3)]23−
Polyoxometalates (POM) are metal oxide cluster compounds with applications in many fields
from medicine to nanotechnology.[1] The wide interest and numerous applications mean …
from medicine to nanotechnology.[1] The wide interest and numerous applications mean …