Criegee intermediates and their impacts on the troposphere
Criegee intermediates (CIs), carbonyl oxides formed in ozonolysis of alkenes, play key roles
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
Theoretical chemical kinetics in tropospheric chemistry: methodologies and applications
L Vereecken, DR Glowacki, MJ Pilling - Chemical reviews, 2015 - ACS Publications
Chemical kinetics is central in much of tropospheric chemistry and in modeling tropospheric
chemical processes. Chemical reaction rate coefficients and product yields have traditionally …
chemical processes. Chemical reaction rate coefficients and product yields have traditionally …
Atmospheric chemistry of Criegee intermediates: Unimolecular reactions and reactions with water
Criegee intermediates are produced in the ozonolysis of unsaturated hydrocarbons in the
troposphere, and understanding their fate is a prerequisite to modeling climate-controlling …
troposphere, and understanding their fate is a prerequisite to modeling climate-controlling …
Water Charge Transfer Accelerates Criegee Intermediate Reaction with H2O– Radical Anion at the Aqueous Interface
Criegee intermediates (CIs) are important carbonyl oxides that may react with atmospheric
trace chemicals and impact the global climate. The CI reaction with water has been widely …
trace chemicals and impact the global climate. The CI reaction with water has been widely …
Unimolecular decay strongly limits the atmospheric impact of Criegee intermediates
Stabilized Criegee intermediates (SCI) are reactive oxygenated species formed in the
ozonolysis of hydrocarbons. Their chemistry could influence the oxidative capacity of the …
ozonolysis of hydrocarbons. Their chemistry could influence the oxidative capacity of the …
The physical chemistry of Criegee intermediates in the gas phase
DL Osborn, CA Taatjes - International Reviews in Physical …, 2015 - Taylor & Francis
Carbonyl oxides, also known as Criegee intermediates, are key intermediates in both gas
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …
Severe atmospheric pollution in the Middle East is attributable to anthropogenic sources
Abstract In the Middle East, desert dust is assumed to dominate air pollution, being in
permanent violation of public health guidelines. Here we present ship-borne measurements …
permanent violation of public health guidelines. Here we present ship-borne measurements …
Rate coefficients of C1 and C2 Criegee intermediate reactions with formic and acetic acid near the collision limit: direct kinetics measurements and atmospheric …
Rate coefficients are directly determined for the reactions of the Criegee intermediates (CI)
CH2OO and CH3CHOO with the two simplest carboxylic acids, formic acid (HCOOH) and …
CH2OO and CH3CHOO with the two simplest carboxylic acids, formic acid (HCOOH) and …
Four-carbon Criegee intermediate from isoprene ozonolysis: Methyl vinyl ketone oxide synthesis, infrared spectrum, and OH production
The reaction of ozone with isoprene, one of the most abundant volatile organic compounds
in the atmosphere, produces three distinct carbonyl oxide species (RR′ COO) known as …
in the atmosphere, produces three distinct carbonyl oxide species (RR′ COO) known as …
Criegee intermediates: production, detection and reactivity
In the context of tropospheric chemistry, Criegee intermediates denote carbonyl oxides with
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …