Nitration of o-xylene in the microreactor: Reaction kinetics and process intensification

S Guo, L Zhan, B Li - Chemical Engineering Journal, 2023 - Elsevier
Nitration reactions are extensively studied in organic synthesis despite their notorious
dangers, high reaction rates, and heterogeneous reaction systems. To date, most industrial …

HNO3/HFIP: A Nitrating System for Arenes with Direct Observation of π-Complex Intermediates

L Lu, H Liu, R Hua - Organic letters, 2018 - ACS Publications
This report describes an efficient nitrating system for the nitration of arenes at room
temperature by using an equivalent of nitric acid in HFIP (1, 1, 1, 3, 3, 3 …

Efficient and selective nitration of xylenes over MoO3/SiO2 supported phosphoric acid

J Adamiak, M Chmielarek - Journal of Industrial and Engineering Chemistry, 2015 - Elsevier
Silica supported molybdenum oxide modified with phosphoric acid (P/Mo/SiO 2) is a very
active solid acid catalyst in ortho-xylene nitration. At room temperature and with a small …

Mesoporous BiCl3 immobilized silicic acid as a stabilized Lewis acid catalyst for the selective synthesis of 4-nitro-o-xylene from the nitration of o-xylene with NO2 …

J Yan, W Fu, K You, F Zhao, H Luo - Reaction Kinetics, Mechanisms and …, 2024 - Springer
A solvent-free, acid-free, and efficient strategy was developed for the selective preparation of
4-nitro-o-xylene (4-NOX) from the catalytic nitration of o-xylene with NO2 mediated O2 over …

Acid-Catalyzed Regioselective Nitration of o-Xylene to 4-Nitro-o-xylene with Nitrogen Dioxide: Brønsted Acid Versus Lewis Acid

B Tang, S Wei, X Peng - Synthetic Communications, 2014 - Taylor & Francis
Nitration of o-xylene with nitrogen dioxide imparts remarkable selectivity to 4-nitro-o-xylene.
The addition of Brønsted acids and Lewis acids can effectively improve the selectivity for 4 …

[PDF][PDF] Zeolite-Assisted Regioselective Synthesis of Dinitronaphthalene

W Shi, X Peng, X Dong, H Wang… - Asian Journal of …, 2012 - chemicalbook.com
Nitration of aromatic compounds is one of the most important chemical reactions and widely
used in chemical industry. Classical nitration based on nitric acid and sulfuric acid is quite …

Diatomite-entrapped hydrosulfate catalysts for the efficient nitration of toluene with nitric acid

CJ Yue, SS Yao, LP Gu - Journal of Porous Materials, 2015 - Springer
Diatomite-entrapped hydrosulfate catalysts with the enhanced acidity were prepared by
impregnation and 20 wt% KHSO 4/diatomite was selected as a heterogeneous catalyst for …

Crystal structure of 1,2-dimethyl-3,5-dinitrobenzene, C8H8N2O4

W Jianlong, X Shaomin, S Fanfan… - … für Kristallographie-New …, 2018 - degruyter.com
Crystal structure of 1,2-dimethyl-3,5- dinitrobenzene, C8H8N2O4 Page 1 Z. Kristallogr. NCS
2018; 233(5): 909–910 Wang Jianlong*, Xue Shaomin, Shen Fanfan and Xu Zishuai Crystal …

[引用][C] 固体酸催化合成硝酸酯反应研究进展

张广林, 王胜平, 黄小红 - 化学试剂, 2010

[引用][C] 间二甲苯的硝化方法

李建东, 李永祥 - 天津化工, 2011