Hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes are widely
utilized in the synthesis of valuable allylic compounds. In the past decades, asymmetric …

This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

After the long-held assumption of the unreactivity of gold, numerous reactions catalyzed by
this noble metal have been increasingly emerging in the literature over the past 2 decades …

Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …

Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis | Chemical Reviews ACS
ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Organolanthanides are highly efficient catalysts for inter-and intramolecular hydroamination
of various C− C unsaturations such as alkenes, alkynes, allenes, and dienes. Attractive …

The piperidine ring is an ubiquitous structural feature of many alkaloid natural products and
drug candidates. Watson et al. asserted that during a recent 10-year period there were …

The hydroamination of unsaturated carbon‐carbon linkages allows a facile and highly atom‐
economical access to industrially relevant nitrogen‐containing basic and fine chemicals as …

The use of the combination of homogeneous gold-catalysts and alkynes in organic synthesis
is reviewed from its beginnings in CN-bond formation to the newest developments in CC …

The β-diketiminate-stabilized calcium amide complex [{ArNC (Me) CHC (Me) NAr} Ca {N
(SiMe3) 2}(THF)](Ar= 2, 6-diisopropylphenyl) and magnesium methyl complex [{ArNC (Me) …