[HTML][HTML] Primary Amine Nucleophilic Addition to Nitrilium Closo-Dodecaborate [B12H11NCCH3]−: A Simple and Effective Route to the New BNCT Drug Design
AV Nelyubin, NA Selivanov, AY Bykov… - International Journal of …, 2021 - mdpi.com
In the present work, a convenient and straightforward approach to the preparation of
borylated amidines based on the closo-dodecaborate anion [B12H11NCCH3NHR]−, R= H …
borylated amidines based on the closo-dodecaborate anion [B12H11NCCH3NHR]−, R= H …
Water-soluble Re 6-clusters with aromatic phosphine ligands–from synthesis to potential biomedical applications
AA Ivanov, DI Konovalov, TN Pozmogova… - Inorganic Chemistry …, 2019 - pubs.rsc.org
The development of water-soluble hexanuclear cluster complexes of low toxicity is a
promising task due to their potential biomedical applications such as bioimaging and …
promising task due to their potential biomedical applications such as bioimaging and …
Synthesis and luminescence properties of apically homoleptic octahedral rhenium clusters with pyrazole and 3, 5-dimethylpyrazole
DI Konovalov, AA Ivanov, YA Vorotnikov… - Inorganica Chimica …, 2019 - Elsevier
Interaction of cluster anions [{Re 6 Q 8} X 6] 4−/3−(Q= S or Se; X= Cl, Br or I) with molten pro-
ligands–pyrazole (pzH) and 3, 5-dimethylpyrazole (3, 5-Me 2 pzH) has led to the formation …
ligands–pyrazole (pzH) and 3, 5-dimethylpyrazole (3, 5-Me 2 pzH) has led to the formation …
Tuning the Ground-and Excited-State Redox Potentials of Octahedral Hexanuclear Rhenium (III) Complexes by the Combination of Terminal Halide and N …
T Yoshimura, H Nishizawa, K Nagata, A Ito… - ACS …, 2022 - ACS Publications
The present study reports that the ground-and excited-state Re6 (23e)/Re6 (24e) redox
potentials of an octahedral hexanuclear rhenium (III) complex can be controlled by …
potentials of an octahedral hexanuclear rhenium (III) complex can be controlled by …
Functionalization of [Re 6 Q 8 (CN) 6] 4− clusters by methylation of cyanide ligands
MA Mikhaylov, AD Mironova, KA Brylev… - New Journal of …, 2019 - pubs.rsc.org
Methylation of anionic cluster complexes [Re6Q8 (CN) 6] 4− with ((CH3) 3O) BF4 or
CF3SO3CH3 afforded homoleptic isonitrile cluster complexes [Re6Q8 (CH3NC) 6] 2+(Q= S …
CF3SO3CH3 afforded homoleptic isonitrile cluster complexes [Re6Q8 (CH3NC) 6] 2+(Q= S …
Phosphorescent complexes of {Mo 6 I 8} 4+ with triazolates:[2+ 3] cycloaddition of alkynes to [Mo 6 I 8 (N 3) 6] 2−
AD Mironova, MA Mikhailov, KA Brylev… - New Journal of …, 2020 - pubs.rsc.org
(Bu4N) 2 [Mo6I8 (N3) 6], prepared in a clean high-yield reaction from (Bu4N) 2 [Mo6I8
(CH3COO) 6] and Me3SiN3, undergoes [3+ 2] cycloaddition with CH3O (O) CC (O) OCH3 …
(CH3COO) 6] and Me3SiN3, undergoes [3+ 2] cycloaddition with CH3O (O) CC (O) OCH3 …
Exploring the Breadth of Terminal Ligands Coordinated in [Mo6X8]4+- and [Re6Q8]2+-Based Cluster Complexes
LF Szczepura, E Soto - Ligated Transition Metal Clusters in Solid-State …, 2019 - Springer
This survey provides an overview of the different types of terminal ligands incorporated into
molybdenum halide and rhenium chalcogenide cluster complexes. While the incorporation …
molybdenum halide and rhenium chalcogenide cluster complexes. While the incorporation …
Soluble molecular rhenium cluster complexes exhibiting multistage terminal ligands reduction
AA Ulantikov, YM Gayfulin, AA Ivanov… - Inorganic …, 2020 - ACS Publications
Substitution of terminal halide ligands of octahedral rhenium cluster complexes [Re6Q8X6] 4–
in a melt of 4, 4′-bipyridine (bpy) led to us obtaining four new compounds with the general …
in a melt of 4, 4′-bipyridine (bpy) led to us obtaining four new compounds with the general …
Octahedral chalcogenide rhenium cluster complexes with imidazole
DI Konovalov, AA Ivanov, YA Vorotnikov… - Polyhedron, 2019 - Elsevier
Abstract Reactions of [{Re 6 Q 8} Br 6] 4−/3−(Q= S, Se) with molten imidazole lead to the
formation of two new neutral cluster complexes [{Re 6 Q 8}(imzH) 4 (imz) 2](imzH …
formation of two new neutral cluster complexes [{Re 6 Q 8}(imzH) 4 (imz) 2](imzH …
Substitution of apical iodide ligands in octahedral molybdenum cluster complexes by N-donor molecules: Synthesis and investigation of [{Mo6I8}(L) I5]–and cis …
AA Ulantikov, KD Podolets, TS Sukhikh, YV Mironov… - Polyhedron, 2024 - Elsevier
In this work, reactivity of the [{Mo 6 I 8} I 6] 2–cluster anion toward some N-donor ligands was
investigated. Heating of the solution of Cs 2 [{Mo 6 I 8} I 6] salt in acetonitrile leads to the …
investigated. Heating of the solution of Cs 2 [{Mo 6 I 8} I 6] salt in acetonitrile leads to the …