Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

Relaxation dynamics of dysprosium (III) single molecule magnets

YN Guo, GF Xu, Y Guo, J Tang - Dalton Transactions, 2011 - pubs.rsc.org
Over the past decade, lanthanide compounds have become of increasing interest in the field
of Single Molecule Magnets (SMMs) due to the large inherent anisotropy of the metal ions …

Modulating single-molecule magnet behavior towards multiple magnetic relaxation processes through structural variation in Dy 4 clusters

WM Wang, XM Kang, HY Shen, ZL Wu… - Inorganic Chemistry …, 2018 - pubs.rsc.org
Three Dy4 clusters,[Dy4 (tmhd) 8 (L) 2 (CH3OH) 2]· CH3OH (1),[Dy4 (hfac) 8 (L) 2 (DMF) 2]·
C7H16 (2) and [Dy4 (dbm) 6 (L) 2 (μ3-OH) 2]· CH2Cl2 (3)(tmhd= 2, 2, 6, 6-tetramethyl-3, 5 …

Lanthanide Single‐molecule Magnets: Synthetic Strategy, Structures, Properties and Recent Advances

J Wang, CY Sun, Q Zheng, DQ Wang… - Chemistry–An Asian …, 2023 - Wiley Online Library
Single‐molecule magnets (SMMs) show wide potential applications in the field of ultrahigh‐
density storage materials, quantum computing, spintronics, and so on. Lanthanide (Ln) …

Coordination-perturbed single-molecule magnet behaviour of mononuclear dysprosium complexes

GJ Chen, CY Gao, JL Tian, J Tang, W Gu, X Liu… - Dalton …, 2011 - pubs.rsc.org
By changing the ratio of reactants, two mononuclear Dy complexes,[Dy (phen)(acac) 3](1)
and [Dy (phen) 2 (NO3) 2 (acac)]· H2O (2) have been synthesized and structurally …

Rhombus-Shaped Tetranuclear [Ln4] Complexes [Ln = Dy(III) and Ho(III)]: Synthesis, Structure, and SMM Behavior

V Chandrasekhar, S Hossain, S Das, S Biswas… - Inorganic …, 2013 - ACS Publications
The reaction of a new hexadentate Schiff base hydrazide ligand (LH3) with rare earth (III)
chloride salts in the presence of triethylamine as the base afforded two planar tetranuclear …

Magnetic anisotropy and mechanism of magnetic relaxation in Er (III) single-ion magnets

SK Singh, T Gupta, G Rajaraman - Inorganic chemistry, 2014 - ACS Publications
Magnetic anisotropy is a key component in the design of single-molecule magnets (SMMs)
possessing a large barrier height for magnetization reversal. Lanthanide-based SMMs are …

Structures and magnetic properties of several phenoxo-O bridged dinuclear lanthanide complexes: Dy derivatives displaying substituent dependent magnetic …

WM Wang, WZ Qiao, HX Zhang, SY Wang, YY Nie… - Dalton …, 2016 - pubs.rsc.org
Nine dinuclear Ln (III) complexes,[Ln (dbm) 2 (L)] 2 (Ln= Eu (1), Tb (2), Dy (3), Ho (4), Er (5))
and [Ln (dbm) 2 (L′)] 2 (Ln= Tb (6), Dy (7), Ho (8), Er (9))(dbm= 1, 3-diphenyl-1, 3 …

Tetranuclear Lanthanide (III) Complexes Containing Dimeric Subunits: Single-Molecule Magnet Behavior for the Dy4 Analogue

V Chandrasekhar, S Das, A Dey, S Hossain… - Inorganic …, 2013 - ACS Publications
The reaction of the lanthanide (III) salts [Dy (III), Tb (III), and Gd (III)] with a hetero donor
chelating ligand N′-(2-hydroxy-3-methoxybenzylidene)-6-(hydroxymethyl) …