Nucleophilic Thiol-yne reaction in Macromolecular Engineering: From synthesis to applications

O Daglar, S Luleburgaz, E Baysak, US Gunay… - European Polymer …, 2020 - Elsevier
The developments in synthetic polymer chemistry have devoted to meet the huge demand
required to create efficient, high yield, and operationally simple chemical methods that can …

Thiolactone chemistry, a versatile platform for macromolecular engineering

N Illy, E Mongkhoun - Polymer Chemistry, 2022 - pubs.rsc.org
Thiolactones are often described as latent thiols. They can be ring-opened by hydroxy or
amine groups releasing thiols, which can further react with a large variety of functional …

Thioester functional polymers

S Aksakal, R Aksakal, CR Becer - Sulfur‐Containing Polymers …, 2021 - Wiley Online Library
Inspired by the abundance and versatility of thioester in nature, much attention has been
paid to thioester functionalized materials, allowing applications that range from responsive …

Extremely rapid polythioether synthesis in the presence of TBD

O Daglar, US Gunay, G Hizal, U Tunca… - Macromolecules, 2019 - ACS Publications
A straightforward, novel, and extremely rapid method is developed for the synthesis of
polythioether based on the reaction of dimethyl acetylenedicarboxylate with electron …

A straightforward method for fluorinated polythioether synthesis

O Daglar, E Cakmakci, US Gunay, G Hizal… - …, 2020 - ACS Publications
The synthesis of fluorinated polymers via efficient routes along with mild experimental
conditions is always desirable in terms of synthetic polymer chemistry. In this work, a …

Thermal and mechanical properties of thiol-ene photocured thermosets containing DOPO-based liquid reactive flame retardant synthesized by metal-free azide-alkyne …

G Sagdic, E Cakmakci, O Daglar, US Gunay… - Progress in Organic …, 2022 - Elsevier
The use of metal-free click reactions for the design and synthesis of novel flame retardant
reactive monomers for thiol-ene photopolymerization is an intriguing area of research. In this …

A facile approach for the fabrication of antibacterial nanocomposites: A case study for AgNWs/Poly (1, 4-Cyclohexanedimethylene Acetylene Dicarboxylate) composite …

C Altinkok, G Acik, O Daglar, H Durmaz, I Tunc… - European Polymer …, 2022 - Elsevier
Nanotechnological improvements allow the production of new generation materials among
which nanocomposite-based polymers are increasingly applied for wide variety of …

Ultrafast synthesis of dialkyne-functionalized polythioether and post-polymerization modification via click chemistry

B Pektas, G Sagdic, O Daglar, S Luleburgaz, US Gunay… - Polymer, 2022 - Elsevier
Herein, we prepare a polythioether with double “clickable” alkyne groups in each repeating
unit via an extremely rapid polymerization method and combine it with Cu (I)-catalyzed azide …

All in one: The preparation of polyester/silica hybrid nanocomposites via three different metal-free click reactions

O Daglar, E Çakmakçi, US Gunay, G Hizal… - European Polymer …, 2021 - Elsevier
The development of innovative routes for the preparation of hybrid polymer nanocomposites
is an active area of research for engineering applications. In this study, we have utilized …

Acetylene dicarboxylic acid diallyl ester: a versatile monomer for thiol–ene photocured networks

O Daglar, E Çakmakçi, US Gunay… - Macromolecular …, 2021 - Wiley Online Library
Thiol–ene photopolymerization (TEP) is a highly advantageous method for the curing of
unsaturated monomers, and the design of novel monomers to be used in TEP is an active …