Noyori–Ikariya‐type ruthenium (II)‐catalysts for asymmetric transfer hydrogenation (ATH)
have been known for 25 years and have proved as a well‐behaved and user‐friendly …

Seven membered heterocyclic Azepine and its derivatives have great pharmacological and
therapeutic implications. In this review, the literature of the last fifty years has been exploited …

A series of α-amino ketones were reduced using asymmetric transfer hydrogenation (ATH)
through a dynamic kinetic resolution (DKR). The protecting group was matched to the …

The utility of tethered Ru-TsDPEN catalyst has been demonstrated for the asymmetric
transfer hydrogenation of rac-α-heteroaryl amino cycloalkanones to construct biologically …

The asymmetric reduction of unsaturated carbonyl functionalities is one of the most
important chemical transformations to generate optically active stereocenters. Optically …

Tethered ruthenium–TsDPEN complexes have been applied to the catalysis of the
asymmetric transfer hydrogenation of a range of aryl/acetylenic ketones. The introduction of …

A series of propanones containing combinations of aryloxy and alkoxy substituents at the 1-
and 3-positions were reduced to the alcohols via asymmetric transfer hydrogenation using a …

The asymmetric transfer hydrogenation (ATH) of α-keto-1, 4-diamides using a tethered
Ru/TsDPEN catalyst was achieved in high ee. Studies on derivatives identified the structural …

This work reports the synthesis of α-hydroxy amide and its derivatives using zirconium-
based metal–organic frameworks (Zr-MOFs). The Zr-MOF was prepared using a ligand …

A dynamic kinetic resolution–asymmetric transfer hydrogenation (DKR‐ATH) methodology
of α‐keto/enol‐lactams was developed. We also propose a possible catalytic mechanism …