Tropospheric aqueous-phase chemistry: kinetics, mechanisms, and its coupling to a changing gas phase

H Herrmann, T Schaefer, A Tilgner, SA Styler… - Chemical …, 2015 - ACS Publications
This Review aims to summarize the current understanding of bulk tropospheric aqueous-
phase chemistry. Because a complete review of all developments in this area would be …

Rate constants of dichloride radical anion reactions with molecules of environmental interest in aqueous solution: A review

L Wojnárovits, E Takács - Environmental Science and Pollution Research, 2021 - Springer
Natural waters, water droplets in the air at coastal regions and wastewaters usually contain
chloride ions (Cl-) in relatively high concentrations in the milimolar range. In the reactions of …

Quantitative structure–activity relationship (QSAR) for the oxidation of trace organic contaminants by sulfate radical

R Xiao, T Ye, Z Wei, S Luo, Z Yang… - … science & technology, 2015 - ACS Publications
The sulfate radical anion (SO4•–) based oxidation of trace organic contaminants (TrOCs)
has recently received great attention due to its high reactivity and low selectivity. In this …

Overlooked impacts of natural organic matter conversion in a Fe (II)-induced peroxymonosulfate activation system for river water remediation

L Liang, G Chen, J Zhao, P Shao, N Li, M He… - Science of The Total …, 2023 - Elsevier
The peroxymonosulfate (PMS) process may be hindered severely due to natural organic
matter (NOM) conversion in the treatment of emerging pollutants from river water, becoming …

Oxidation reactions of 1-and 2-naphthols: an experimental and theoretical study

R Sreekanth, KP Prasanthkumar… - The Journal of …, 2013 - ACS Publications
The transients formed during the reactions of oxidizing radicals with 1-naphthol (1) and 2-
naphthol (2) in aqueous medium have been investigated by pulse radiolysis with detection …

Odd-electron-bonded sulfur radical cations: x-ray structural evidence of a sulfur–sulfur three-electron σ-bond

S Zhang, X Wang, Y Sui, X Wang - Journal of the American …, 2014 - ACS Publications
The one-electron oxidations of 1, 8-chalcogen naphthalenes Nap (SPh) 2 (1) and Nap
(SPh)(SePh)(2) lead to the formation of persistent radical cations 1•+ and 2•+ in solution …

Identifying the Transients and Transformation Products in Hydroxyl Radical–Methimazole Reactions Using DFT and UPLC-Q-TOF MS/MS Approaches

KP Prasanthkumar, F Valayankadan… - The Journal of …, 2024 - ACS Publications
Oxidative reactions of the hydroxyl radical (· OH) with methimazole (MMI), an antithyroid
drug, are crucial for understanding its fate in oxidizing environments. By synergistically …

Insights into the mechanism of hydroxyl radical mediated oxidations of 2-aminopurine: a computational and sonochemical product analysis study

KP Prasanthkumar, MP Rayaroth… - The Journal of …, 2020 - ACS Publications
Mechanistic details of hydroxyl radical (• OH) mediated oxidations of 2-aminopurine (2AP) in
the aqueous phase have been established in this study via a combination of DFT …

An experimental and theoretical study of the kinetics and mechanism of hydroxyl radical reaction with 2-aminopyrimidine

KP Prasanthkumar, JR Alvarez-Idaboy - RSC Advances, 2014 - pubs.rsc.org
Oxidation of 2-aminopyrimidine (2Apy) by hydroxyl radicals (˙ OH) in aqueous medium has
been studied using pulse radiolysis coupled to optical absorption and M05-2X/6-311++ G (d …

[HTML][HTML] Communication: Electronic UV-Vis transient spectra of the· OH reaction products of uracil, thymine, cytosine, and 5, 6-dihydrouracil by using the complete …

A Francés-Monerris, M Merchán… - The Journal of Chemical …, 2013 - pubs.aip.org
Addition of· OH radicals to pyrimidine nucleobases is a common reaction in DNA/RNA
damage by reactive oxygen species. Among several experimental techniques, transient …