Hydration of a synthetic clay with tetrahedral charges: a multidisciplinary experimental and numerical study

E Rinnert, C Carteret, B Humbert… - The Journal of …, 2005 - ACS Publications
The interaction of water with a synthetic saponite clay sample, with a layer charge of 1 per
unit cell (0.165 C m-2), was investigated by following along water adsorption and desorption …

Ionic mobility and hydration energies in montmorillonite clay

F Salles, S Devautour-Vinot, O Bildstein… - The Journal of …, 2008 - ACS Publications
The structure of swelling clays consists of a framework composed of negatively charged clay
platelets and interlayer cations. Swelling clays present different behaviors as a function of …

Activation energy for dc conductivity in dehydrated alkali metal-exchanged montmorillonites: experimental results and model

A Haouzi, M Kharroubi, H Belarbi, S Devautour-Vinot… - Applied clay …, 2004 - Elsevier
The ac conductivity of a series of dehydrated alkali metal-exchanged (Li+, Na+, K+, Rb+,
and Cs+) montmorillonites has been measured at different temperatures, and the activation …

Thermodynamic analysis of the immersion of a swelling clay

V Médout-Marère, H Belarbi, P Thomas… - Journal of colloid and …, 1998 - Elsevier
In this paper we present an analysis of the surface of an Algerian montmorillonite. We use
two classical methods and we develop two new methods of following the variation of the …

Interlayer cation–water thermodynamics and dynamics in homoionic alkali and alkaline-earth exchanged montmorillonites with low water loadings

M Kharroubi, S Balme, A Haouzi… - The Journal of …, 2012 - ACS Publications
Dehydration enthalpy and dc conductivity obtained by means of thermogravimetric analysis
and complex impedance spectroscopy respectively on three alkaline-earth, ie Mg2+, Ca2+ …

Influence of framework Si/Al ratio on the Na+/mordenite interaction energy

M Pamba, G Maurin, S Devautour… - Physical Chemistry …, 2000 - pubs.rsc.org
A direct synthesis of Na-mordenite, characterized by Si/Al ratios ranged from 5.5 to 12,
without introducing any organic compounds, is reported. The effect of aluminium …

Non-Arrhenian ionic DC conductivity of homoionic alkali exchanged montmorillonites with low water loadings

S Balme, M Kharroubi, A Haouzi… - The Journal of Physical …, 2010 - ACS Publications
Dc conductivity of the whole series of homoionic alkali exchanged montmorillonites is
investigated by means of Complex Impedance Spectroscopy. Conductivity of the samples is …

Application of the Electronegativity Equalization Method to the Interpretation of TSDC Results:  Case of a Mordenite Exchanged by Na+ and Li+ Cations

S Devautour, JC Giuntini, F Henn… - The Journal of …, 1999 - ACS Publications
The work presented here proposes a new interpretative method for thermally stimulated
depolarization current (TSDC) measurements. By applying the concept of electronegativity …

[PDF][PDF] Engineered barrier system research activities at lbnl: Fy20 progress report

LG Zheng, L Lammers, P Fox, C Tournassat… - 2020 - escholarship.org
The design of a radioactive waste repository typically involves a multi-barrier system,
including the natural barrier system (NBS), ie, the host rock and its surrounding subsurface …

Dynamic coupling effects in frictional geomaterials—Stochastic resonance

YH Wang, JC Santamarina - Journal of geotechnical and …, 2002 - ascelibrary.org
Nonlinear, dynamic coupling effects and the manifestation of stochastic resonance are
explored in the context of frictional geomaterials. The first experiment is designed to study a …