This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …

Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Enabling the rational synthesis of molecular candidates for quantum information processing
requires design principles that minimize electron spin decoherence. Here we report a …

In this critical review we review the problem of exchange interactions in polynuclear metal
complexes involving orbitally degenerate metal ions. The key feature of these systems is …

Recent studies revealed that magnetic molecules with single spin centers showed exciting
phenomena related to quantum information processing, such as long quantum coherence …

We describe frequency-domain Fourier-transform THz-EPR as a method to assign spin-
coupling parameters of high-spin (S> 1/2) systems with very large zero-field splittings. The …

We have investigated the single‐molecule magnets [MnIII2 (5‐Brsalen) 2 (MeOH) 2MIII (CN)
6] NEt4 (M= Os (1) and Ru (2); 5‐Brsalen= N, N′‐ethylenebis (5‐bromosalicylidene) …

This article overviews the current state and prospects of the concept of advanced single-
molecule magnets (SMMs) based on low-spin (S= 1/2) pentagonal-bipyramidal (PBP) 4d3 …

Pentanuclear cyanide-bridged clusters of the general formula {[M (tmphen) 2] 3 [M′(CN) 6]
2}(tmphen= 3, 4, 7, 8-tetramethyl-1, 10-phenanthroline) have been under investigation in our …