[HTML][HTML] Surface organometallic and coordination chemistry toward single-site heterogeneous catalysts: strategies, methods, structures, and activities

C Coperet, A Comas-Vives, MP Conley… - Chemical …, 2016 - ACS Publications
The chemical industry relies on catalytic processes, which involve mainly heterogeneous
catalysts because they offer many advantages over their homogeneous counterparts such …

Computational modeling of heterogeneous Ziegler-Natta catalysts for olefins polymerization

N Bahri-Laleh, A Hanifpour, SA Mirmohammadi… - Progress in Polymer …, 2018 - Elsevier
Abstract Since 1963, when Karl Ziegler and Giulio Natta were jointly awarded the Nobel
Prize for their discoveries of the catalytic polymerization of olefins with Ti-chlorides and Al …

Nontraditional catalyst supports in surface organometallic chemistry

RJ Witzke, A Chapovetsky, MP Conley… - ACS …, 2020 - ACS Publications
The field of Surface Organometallic Chemistry (SOMC) aims to blend the positive attributes
of homogeneous and heterogeneous catalysis. Significant insight into heterogeneous …

Surface Oxalate Coordination: Facilitating Basic OER Activity by Regulating the Electronic Structure of Fe–Ni3S2

W Xu, C Zhang, H Shen, X Ma, Z Cheng… - ACS Sustainable …, 2022 - ACS Publications
Oxalate-coordinated transition metal-based electrocatalysts have recently been shown to be
very efficient for oxygen evolution reaction (OER). However, the role of oxalate ligands has …

Synthetic, layered nanoparticles for polymeric nanocomposites (PNCs)

LA Utracki, M Sepehr… - Polymers for advanced …, 2007 - Wiley Online Library
This review discusses preparation and use of the synthetic layered nanoparticles in polymer
matrices, ie, in the polymeric nanocomposites (PNCs). Several types of synthetic or semi …

Novel FeNi‐Based Nanowires Network Catalyst Involving Hydrophilic Channel for Oxygen Evolution Reaction

X Qiao, H Kang, Y Li, K Cui, X Jia, X Wu, W Qin - Small, 2022 - Wiley Online Library
Developing novel, efficient, and low‐cost 3D FeNi‐based oxygen evolution reaction (OER)
catalysts with the special hydrophilic channel is still a challenge for improving hydrogen …

A periodic hybrid DFT approach (including dispersion) to MgCl2-supported Ziegler–Natta catalysts–1: TiCl4 adsorption on MgCl2 crystal surfaces

M D'Amore, R Credendino, PHM Budzelaar, M Causá… - Journal of catalysis, 2012 - Elsevier
The adsorption of TiCl4 on the surfaces of MgCl2 crystals has been investigated by means
of state-of-the-art periodic hybrid DFT methods, as the first step of a comprehensive study …

Porous 3D polymers for high pressure methane storage and carbon dioxide capture

S Bracco, D Piga, I Bassanetti, J Perego… - Journal of Materials …, 2017 - pubs.rsc.org
High surface area 3D polymers represent one of the most promising classes of porous
materials because of their high gas uptake and stability to thermal and chemical …

[HTML][HTML] Exploring microstructure of MgCl2· nEtOH adducts for Ziegler-Natta catalysts

R Bazvand, N Bahri-Laleh, H Abedini… - Journal of Molecular …, 2023 - Elsevier
The activation of MgCl 2 through the formation of MgCl 2· nEtOH adducts is considered the
principal step for the preparation of high performance Ziegler-Natta catalysts for olefins …

Influence of the ethanol content of adduct on the Comonomer incorporation of related Ziegler–Natta catalysts in propylene (Co) polymerizations

M Mehdizadeh, F Karkhaneh, M Nekoomanesh… - Polymers, 2023 - mdpi.com
The aim of this work is to investigate the influence of the ethanol content of adducts on the
catalytic behavior of related Ziegler–Natta (ZN) catalysts in propylene homo-and …