Organocatalytic tail-to-tail dimerization of olefin: umpolung of methyl methacrylate mediated by N-heterocyclic carbene

S Matsuoka, Y Ota, A Washio, A Katada, K Ichioka… - Organic …, 2011 - ACS Publications
Highly selective tail-to-tail dimerization of methyl methacrylate has been realized by an N-
heterocyclic carbene catalyst, giving dimethyl 2, 5-dimethyl-2-hexenedioate with an E/Z ratio …

Oxidative coupling reactions at ruthenium (0) and their applications to catalytic homo-and cross-dimerizations¶

M Hirano, S Komiya - Coordination Chemistry Reviews, 2016 - Elsevier
Aspects of the chemistry of zero-valent ruthenium complexes having a cyclic diene ligand,
and their use for homo-and cross-dimerizations are reviewed. The naphthalene ligand in …

Recent advances in the catalytic linear cross-dimerizations

M Hirano - ACS Catalysis, 2019 - ACS Publications
Catalytic cross-dimerization is one of the powerful synthetic methods to produce linear
molecules with high atom and step economy. Because this process involves a carbon …

Reactivity of a Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO2

T Ito, K Takahashi, N Iwasawa - Organometallics, 2018 - ACS Publications
By using a zerovalent, electron-rich ruthenium complex bearing a tetradentate phosphine
ligand, a five-membered ruthenalactone was generated by oxidative cyclization of ethylene …

Cooperative N-heterocyclic carbene/Brønsted acid catalysis for the tail-to-tail (co) dimerization of methacrylonitrile

T Kato, S Matsuoka, M Suzuki - The Journal of Organic Chemistry, 2014 - ACS Publications
The first tail-to-tail dimerization of methacrylonitrile (MAN) has been realized by the
cooperative use of N-heterocyclic carbene (NHC) and Brønsted acid catalysts, producing 2 …

Development of ruthenium-based complexes as anticancer agents: Toward a rational design of alternative receptor targets

AA Adeniyi, PA Ajibade - Reviews in Inorganic Chemistry, 2016 - degruyter.com
In the search for novel anticancer agents, the development of metal-based complexes that
could serve as alternatives to cisplatin and its derivatives has received considerable …

Ruthenium-catalyzed cross-coupling of maleimides with alkenes

T Morita, M Akita, T Satoh, F Kakiuchi, M Miura - Organic letters, 2016 - ACS Publications
Ruthenium-Catalyzed Cross-Coupling of Maleimides with Alkenes | Organic Letters ACS ACS
Publications C&EN CAS Find my institution Log In Organic Letters ACS Publications. Most …

Exploring Bis (cyclometalated) Ruthenium (II) Complexes as Active Catalyst Precursors: Room‐Temperature Alkene–Alkyne Coupling for 1, 3‐Diene Synthesis

J Zhang, A Ugrinov, Y Zhang… - Angewandte Chemie …, 2014 - Wiley Online Library
Described is the development of a new class of bis (cyclometalated) ruthenium (II) catalyst
precursors for C C coupling reactions between alkene and alkyne substrates. The complex …

Regio-and enantioselective linear cross-dimerizations between conjugated dienes and acrylates catalyzed by new Ru (0) complexes

Y Hiroi, N Komine, S Komiya, M Hirano - Organometallics, 2014 - ACS Publications
New naphthalene complexes of Ru (0) with various Ru (η6-naphthalene)(cyclic diene)(3)
ligands catalyze linear cross-dimerization between conjugated dienes and acrylates. One of …

N-Heterocyclic carbene-catalyzed cyclotetramerization of acrylates

S Matsuoka, S Namera, A Washio, K Takagi… - Organic …, 2013 - ACS Publications
N-Heterocyclic carbenes (NHCs) were found to catalyze the unprecedented
cyclotetramerization of acrylates, producing the trisubstituted cyclopentenones in moderate …