Hydrogenases

W Lubitz, H Ogata, O Rudiger, E Reijerse - Chemical reviews, 2014 - ACS Publications
The reaction takes place at a specialized metal center that dramatically increases the acidity
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …

[图书][B] Electroanalytical Chemistry: A Series of Advances: Volume 23

AJ Bard, CG Zoski - 2010 - taylorfrancis.com
Electroanalytical chemists and others are concerned not only with the application of new
and classical techniques to analytical problems, but also with the fundamental theoretical …

Peptide self‐assembly as a strategy for facile immobilization of redox enzymes on carbon electrodes

I Grinberg, O Ben‐Zvi, L Adler‐Abramovich… - Carbon …, 2023 - Wiley Online Library
Redox–enzyme‐mediated electrochemical processes such as hydrogen production,
nitrogen fixation, and CO2 reduction are at the forefront of the green chemistry revolution. To …

Biohydrogen for a New Generation of H2/O2 Biofuel Cells: A Sustainable Energy Perspective

A de Poulpiquet, D Ranava, K Monsalve… - …, 2014 - Wiley Online Library
Among sustainable alternatives to fossil fuel, proton exchange membrane fuel cells are
promising devices that deliver electricity from hydrogen and oxygen, producing only water …

The crystalline state as a dynamic system: IR microspectroscopy under electrochemical control for a [NiFe] hydrogenase

PA Ash, SET Kendall-Price, RM Evans, SB Carr… - Chemical …, 2021 - pubs.rsc.org
Controlled formation of catalytically-relevant states within crystals of complex
metalloenzymes represents a significant challenge to structure–function studies. Here we …

Comparison of carbon materials as electrodes for enzyme electrocatalysis: hydrogenase as a case study

J Quinson, R Hidalgo, PA Ash, F Dillon, N Grobert… - Faraday …, 2014 - pubs.rsc.org
We present a study of electrocatalysis by an enzyme adsorbed on a range of carbon
materials, with different size, surface area, morphology and graphitic structure, which are …

Electrocatalysis by hydrogenases: lessons for building bio-inspired device

IJ McPherson, KA Vincent - Journal of the Brazilian Chemical Society, 2014 - SciELO Brasil
A number of redox enzymes function as excellent electrocatalysts when attached to
electrodes or conductor/semi-conductor surfaces. A particular focus of this review is on …

C2-symmetric benzene-based low molecular weight hydrogel modified electrode for highly sensitive detection of copper ions

W Cai, C Feng, X Ma, M Chen, J Liu - Electrochimica Acta, 2015 - Elsevier
In this paper, a new type of low molecular weight gelators (LMWGs), C2-symmetric benzene-
based hydrogel (C2-BHG) with a 1, 4-dimine benzene was self-assembled on glassy carbon …

Carbon nanoparticulate films as effective scaffolds for mediatorless bioelectrocatalytic hydrogen oxidation

K Szot, A de Poulpiquet, A Ciaccafava, H Marques… - Electrochimica …, 2013 - Elsevier
Hydrophilic carbon nanoparticles were utilized as an electroconductive and adsorbent
material for membrane-bound [NiFe] hydrogenase obtained from Aquifex aeolicus. Herein, a …

Energy conversion based on bio (electro) catalysts

T Vidaković-Koch - Springer Handbook of Electrochemical Energy, 2017 - Springer
Redox enzymes can be efficiently coupled with an electrode surface giving prospect of
highly efficient and selective bio (electrochemical) transformations for energy conversion …