Polyhalogen and polyinterhalogen anions from fluorine to iodine

K Sonnenberg, L Mann, FA Redeker… - Angewandte Chemie …, 2020 - Wiley Online Library
This Review deals with the evolving field of polyhalogen chemistry, specifically polyhalogen
anions (polyhalides). In addition to a historical outline, current progress in synthetic …

[HTML][HTML] Fluoride ion donor ability of binary fluorides towards the Lewis acids AsF5 and SbF5

Z Mazej - Journal of Fluorine Chemistry, 2023 - Elsevier
The ability of binary fluorides (MF x, x= 1-7) to donate fluoride ions to the Lewis acids AsF 5
and SbF 5, ie, the synthesis and characterization of solids with emphasis on structural data …

Bromine Pentafluoride BrF5, the Formation of [BrF6] Salts, and the Stereochemical (In)activity of the Bromine Lone Pairs

M Möbs, T Graubner, K Eklund… - … A European Journal, 2022 - Wiley Online Library
BrF5 can be prepared by treating BrF3 with fluorine under UV light in the region of 300 to
400 nm at room temperature. It was analyzed by UV‐Vis, NMR, IR and Raman spectroscopy …

Noncovalent sulfoxide–nitrile coupling involving four-center heteroleptic dipole–dipole interactions between the sulfinyl and nitrile groups

DM Ivanov, SV Baykov, AS Novikov… - Crystal Growth & …, 2020 - ACS Publications
The 4-X-5-nitro substituted phthalodinitriles (X= Br 1, I 2) were crystallized from Me2SO
solutions affording crystalline adducts (1–2)· Me2SO, which were characterized by X-ray …

Polyhalogen‐und Polyinterhalogen‐Anionen von Fluor bis Iod

K Sonnenberg, L Mann, FA Redeker… - Angewandte …, 2020 - Wiley Online Library
Dieser Aufsatz widmet sich dem wachsenden Gebiet der Polyhalogen‐Chemie und
insbesondere den Polyhalogen‐Anionen (Polyhalogenide). Neben einem historischen …

Investigation of Isolated IrF5, IrF6 Anions and M[IrF6] (M=Na, K, Rb, Cs) Ion Pairs by Matrix‐Isolation Spectroscopy and Relativistic Quantum‐Chemical …

Y Lu, A Wodyński, M Reimann, R Medel… - … A European Journal, 2024 - Wiley Online Library
Abstract The molecular IrF5−, IrF6− anions and M [IrF6](M= Na, K, Rb, Cs) ion pairs were
prepared by co‐deposition of laser‐ablated alkali metal fluorides MF with IrF6 and isolated …

Formation of metallic Ag on AgBr by femtosecond laser irradiation

L Cabral, J Andrés, E Longo, MA San-Miguel… - Physchem, 2022 - mdpi.com
Laser irradiation of materials induces changes in their structure and functional properties. In
this work, lattice heating and electronic excitation on silver bromide (AgBr), provoked by …

Uranium Cyanides from Reactions in Liquid Ammonia Solution

T Graubner, SS Rudel, SI Ivlev… - European Journal of …, 2024 - Wiley Online Library
Reactions of uranium tri‐and tetrahalides, UBr3, UI3, UCl4, and UI4, with different cyanides
MCN (M= K, Ag) in liquid anhydrous ammonia led to three novel uranium (IV) cyanide …

Beyond Elemental Fluorine: Investigations of High Potential Oxidizers, Non-Classical Fluorine Complexes and the Simons Process

G Senges - 2023 - refubium.fu-berlin.de
Die Oxidation von Xenon mit elementarem Fluor gelingt durch Aktivierung mittels
Bestrahlung, Erhitzen oder elektrischer Entladung. Alternativ kann die Oxidation von Xenon …

Multiple Noncovalent Binding in the Intermediates and Products of the Reaction of N, N-Dimethylformamide with Bromine

OM Zarechnaya, VA Mikhailov - Žurnal obŝej himii, 2024 - journals.rcsi.science
Reaction of nonionic N, N-dimethylformamide (DMF) with bromine under controllable
conditions leads to a number of ionic compounds, mainly to bis (N, N-dimethylformamide) …