3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Recent Advances in Mn, Fe, Co, and Ni-Catalyzed Organic Reactions

LJ Li, Y He, Y Yang, J Guo, Z Lu, C Wang… - CCS …, 2024 - chinesechemsoc.org
This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …

Late‐Stage Diversification through Manganese‐Catalyzed C− H Activation: Access to Acyclic, Hybrid, and Stapled Peptides

N Kaplaneris, T Rogge, R Yin, H Wang… - Angewandte …, 2019 - Wiley Online Library
Bioorthogonal C− H allylation with ample scope was accomplished through a versatile
manganese (I)‐catalyzed C− H activation for the late‐stage diversification of structurally …

Highly selective synthesis of 1, 3-enynes, pyrroles, and furans by manganese (I)-catalyzed C–H activation

S Cembellín, T Dalton, T Pinkert, F Schäfers… - ACS …, 2019 - ACS Publications
A highly selective Mn (I)-catalyzed alkenylation of arenes and heteroarenes with 1, 3-diynes
is described. The reported transformation overcomes regio-, chemo-, and stereoselectivity …

Manganese‐catalyzed hydrosilylation reactions

X Yang, C Wang - Chemistry–An Asian Journal, 2018 - Wiley Online Library
Over the past few decades, manganese‐catalyzed hydrosilylation of C= O or C= C/C≡ C
unsaturated bonds have undergone enormous developments. In this focus review, the …

Merging manganese and iminium catalysis: selective hydroalkenylation of unsaturated aldehydes and ketones

CG Zhao, C Du, Z Guo, W Li, J Han… - Angewandte Chemie, 2023 - Wiley Online Library
The use of synergistic catalytic strategy can usually circumvent the intrinsic limitations of one
catalytic system. In this communication, we disclose a cooperative catalysis strategy of …

Continuous Visible‐Light Photoflow Approach for a Manganese‐Catalyzed (Het) Arene C− H Arylation

YF Liang, R Steinbock, L Yang… - Angewandte …, 2018 - Wiley Online Library
Manganese photocatalysts enabled versatile room‐temperature C− H arylation reactions by
means of continuous visible‐light photoflow, thus allowing for efficient C− H arylations in 30 …

Recent advances in manganese-catalysed C–H activation: scope and mechanism

R Cano, K Mackey, GP McGlacken - Catalysis Science & Technology, 2018 - pubs.rsc.org
As a synthetic methodology, C–H activation represents a complimentary protocol to
traditional cross-couplings such as the Suzuki–Miyaura and Stille reactions, by avoiding the …

Manganese-catalyzed [4+ 2] annulation of N–H amidines with vinylene carbonate via C–H activation

Y Li, H Wang, Y Li, Y Li, Y Sun, C Xia… - The Journal of Organic …, 2021 - ACS Publications
Manganese-catalyzed C–H bond functionalization of aryl amidines for the synthesis of 1-
aminoisoquinolines in the presence of vinylene carbonate has been developed. The …