Absolute frequency metrology of buffer-gas-cooled molecular spectra at 1 kHz accuracy level

R Aiello, V Di Sarno, MG Delli Santi, M De Rosa… - Nature …, 2022 - nature.com
By reducing both the internal and translational temperature of any species down to a few
kelvins, the buffer-gas-cooling (BGC) technique has the potential to dramatically improve the …

[HTML][HTML] The W2020 database of validated rovibrational experimental transitions and empirical energy levels of water isotopologues. II. H217O and H218O with an …

T Furtenbacher, R Tóbiás, J Tennyson… - Journal of Physical …, 2020 - pubs.aip.org
The W2020 database of validated experimental transitions and accurate empirical energy
levels of water isotopologues, introduced in the work of Furtenbacher et al.[J. Phys. Chem …

[HTML][HTML] A short guide to recent developments in laser-based gas phase spectroscopy, applications, and tools

V Shumakova, OH Heckl - APL Photonics, 2024 - pubs.aip.org
This article provides an overview of laser-based absorption spectroscopy applications and
discusses the parameter space and requirements of laser systems for each of these …

On the 12 C 2 H 2 near-infrared spectrum: absolute transition frequencies and an improved spectroscopic network at the kHz accuracy level

A Castrillo, E Fasci, T Furtenbacher… - Physical Chemistry …, 2023 - pubs.rsc.org
Lamb dips of twenty lines in the P, Q, and R branches of the ν1+ ν3+ ν41 vibrational band of
12C2H2, in the spectral window of 7125–7230 cm− 1, have been measured using an …

Spectroscopic-network-assisted precision spectroscopy and its application to water

R Tóbiás, T Furtenbacher, I Simkó, AG Császár… - Nature …, 2020 - nature.com
Frequency combs and cavity-enhanced optical techniques have revolutionized molecular
spectroscopy: their combination allows recording saturated Doppler-free lines with ultrahigh …

SI-traceable molecular transition frequency measurements at the 10−12 relative uncertainty level

ZD Reed, DA Long, H Fleurbaey, JT Hodges - Optica, 2020 - opg.optica.org
Accurate and spectroscopic measurements of molecular transition frequencies are
increasingly being employed in a variety of rigorous tests of physics, including the validity of …

The W2024 database of the water isotopologue

T Furtenbacher, R Tóbiás, J Tennyson, RR Gamache… - Scientific Data, 2024 - nature.com
The rovibrational spectrum of the water molecule is the crown jewel of high-resolution
molecular spectroscopy. While its significance in numerous scientific and engineering …

All paths lead to hubs in the spectroscopic networks of water isotopologues H216O and H218O

R Tóbiás, ML Diouf, FMJ Cozijn, W Ubachs… - Communications …, 2024 - nature.com
Network theory has fundamentally transformed our comprehension of complex systems,
catalyzing significant advances across various domains of science and technology. In …

[HTML][HTML] Communication: Molecular near-infrared transitions determined with sub-kHz accuracy

J Wang, YR Sun, LG Tao, AW Liu… - The Journal of Chemical …, 2017 - pubs.aip.org
Precise molecular transition frequencies are needed in various studies including the test of
fundamental physics. Two well isolated ro-vibrational transitions of 12 C 16 O at 1.57 μ m, R …

Lamb dip CRDS of highly saturated transitions of water near 1.4 μm

S Kassi, T Stoltmann, M Casado, M Daëron… - The Journal of …, 2018 - pubs.aip.org
Doppler-free saturated-absorption Lamb dips were measured at sub-Pa pressures on
rovibrational lines of H 2 16 O near 7180 cm− 1, using optical feedback frequency stabilized …