Solid-state NMR with magic-angle spinning (MAS) is an important method in structural biology. While NMR can provide invaluable information about local geometry on an atomic …
Dynamic Nuclear Polarization (DNP) has recently emerged as a cornerstone approach to enhance the sensitivity of solid-state NMR spectroscopy under Magic Angle Spinning (MAS) …
Despite the expanding applications of dynamic nuclear polarization (DNP) to problems in biological and materials science, there remain unresolved questions concerning DNP …
Dynamic nuclear polarization (DNP) can amplify the solid-state nuclear magnetic resonance (NMR) signal by several orders of magnitude. The mechanism of DNP utilizing α, γ …
Q Stern, G Verhaeghe, T El Daraï… - Angewandte Chemie …, 2024 - Wiley Online Library
The low sensitivity of liquid‐state nuclear magnetic resonance (NMR) can be overcome by hyperpolarizing nuclear spins by dissolution dynamic nuclear polarization (dDNP). It …
The Overhauser effect is unique among DNP mechanisms in that it requires the modulation of the electron–nuclear hyperfine interactions. While it dominates DNP in liquids and metals …
AA Kuzhelev, D Dai, V Denysenkov… - Journal of the American …, 2022 - ACS Publications
Dynamic nuclear polarization (DNP) is a powerful method to enhance NMR sensitivity. Much progress has been achieved recently to optimize DNP performance at high magnetic fields …
We propose a mechanism for dynamic nuclear polarization that is different from the well- known Overhauser effect, solid effect, cross effect, and thermal mixing processes. We term it …
The dielectric properties of materials play a crucial role in the propagation and absorption of microwave beams employed in Magic Angle Spinning− Dynamic Nuclear Polarization (MAS …