[FeFe]-Hydrogenases: maturation and reactivity of enzymatic systems and overview of biomimetic models

JT Kleinhaus, F Wittkamp, S Yadav… - Chemical Society …, 2021 - pubs.rsc.org
While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Synthesis of diiron (I) dithiolato carbonyl complexes

Y Li, TB Rauchfuss - Chemical reviews, 2016 - ACS Publications
Virtually all organosulfur compounds react with Fe (0) carbonyls to give the title complexes.
These reactions are reviewed in light of major advances over the past few decades, spurred …

Taming the Dichalcogenides: Isolation, Characterization, and Reactivity of Elusive Perselenide, Persulfide, Thioselenide, and Selenosulfide Anions

K Li, LN Zakharov, MD Pluth - Journal of the American Chemical …, 2023 - ACS Publications
Reactive sulfur species (RSS) and reactive selenium species (RSeS) play integral roles in
hydrogen sulfide (H2S) and hydrogen selenide (H2Se) biological signaling pathways, and …

Iron carbonyl compounds with aromatic dithiolate bridges as organometallic mimics of [FeFe] hydrogenases

S Gao, Y Liu, Y Shao, D Jiang, Q Duan - Coordination Chemistry Reviews, 2020 - Elsevier
Recently, substantial efforts had been made in the field of synthetic iron compounds as
structural and functional models of the hydrogenase enzyme active site for the purpose of …

[FeFe]-Hydrogenase H-cluster mimics mediated by naphthalene monoimide derivatives of peri-substituted dichalcogenides

H Abul-Futouh, Y Zagranyarski, C Müller… - Dalton …, 2017 - pubs.rsc.org
Synthetic models of the active site of [FeFe]-hydrogenase containing naphthalene
monoimide (NMI) of peri-substituted dichalcogenides as bridging linkers have been …

Brief survey of diiron and monoiron carbonyl complexes and their potentials as CO-releasing molecules (CORMs)

X Jiang, Z Xiao, W Zhong, X Liu - Coordination Chemistry Reviews, 2021 - Elsevier
Iron carbonyl complexes are a large category of classic transition metal complexes. In
addition to their vast range of applications in catalysis, they have been found to be of …

[FeFe]-Hydrogenase H-Cluster Mimics with Various −S(CH2)nS– Linker Lengths (n = 2–8): A Systematic Study

H Abul-Futouh, LR Almazahreh, MK Harb… - Inorganic …, 2017 - ACS Publications
The effect of the nature of the dithiolato ligand on the physical and electrochemical
properties of synthetic H-cluster mimics of the [FeFe]-hydrogenase is still of significant …

Bioinspired Metal Selenolate Polymers with Tunable Mechanistic Pathways for Efficient H2 Evolution

CA Downes, SC Marinescu - ACS Catalysis, 2017 - ACS Publications
The efficient reduction of water into hydrogen has emerged as an attractive strategy for the
conversion of solar energy into chemical bonds. Hydrogenase enzymes efficiently catalyze …

HER catalysed by iron complexes without a Fe2S2 core: A review

T Agarwal, S Kaur-Ghumaan - Coordination Chemistry Reviews, 2019 - Elsevier
The field of proton reduction by iron complexes without thiolate bridging ligand (s) in
homogeneous systems is reviewed. Till date electrocatalytic proton reduction by iron …

[FeFe]-hydrogenase H-cluster mimics mediated by ferrocenyl hetaryl thioketone derivatives

I Basma, H Abul-Futouh, SJ Abaalkhail… - Journal of Molecular …, 2024 - Elsevier
In this report, the influence of the substitution decoration in ferrocenyl selenophen-2-yl
thioketone (1) and ferrocenyl furan-2-yl thioketone (2) utilized as a proligand in …