The last 15 years of hydroformylation and carbonylation chemistry are reviewed, including
technical and commercial aspects.

Although known since the 1950s, free‐radical carbonylation has not received much attention
until only recently. In the last few years the application of modern free‐radical techniques …

The boraformylation of allenes with B2 (pin) 2 and a formate ester as boron and formyl
source, respectively, proceeds in the presence of a copper catalyst. The reaction selectively …

Vinylsilanes are versatile synthetic building blocks, which in recent years have played an
increasing role in the synthesis of complex molecules. This article provides an overview of …

A Rh‐catalyzed reaction of silacyclobutanes (SCBs) with unactivated alkynes has been
developed to form silacyclohexenes with high chemoselectivity. Good enantioselectivity at …

An important focus of organometallic research has been the development and study of
transition metal complexes as catalysts for transformations of organic compounds. These …

This review seeks to evaluate the role of low oxidation state transition metal clusters (metal
carbonyl clusters) in catalysis. The review commences with a discussion of the cluster …

Hydrosilylation, especially of carbon carbon multiple bonds, is one of the most important
reactions in organosilicon chemistry, and thus the reaction has been studied extensively for …

The reaction of 1‐alkenes with carbon monoxide and hydrogen in the presence of a catalyst
gives the corresponding homologous aldehydes. The discovery of this reaction was made …

The Temporary Silicon Connection transforms a potential intermolecular reaction into an
intramolecular one, by transiently connecting both partners through a silicon linkage. In …