Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and …

JA Rodriguez, DC Grinter, Z Liu… - Chemical Society …, 2017 - pubs.rsc.org
Model metal/ceria and ceria/metal catalysts have been shown to be excellent systems for
studying fundamental phenomena linked to the operation of technical catalysts. In the last …

Catalytic reforming of oxygenates: state of the art and future prospects

D Li, X Li, J Gong - Chemical reviews, 2016 - ACS Publications
This Review describes recent advances in the design, synthesis, reactivity, selectivity,
structural, and electronic properties of the catalysts for reforming of a variety of oxygenates …

Highly Active Ceria-Supported Ru Catalyst for the Dry Reforming of Methane: In Situ Identification of Ruδ+–Ce3+ Interactions for Enhanced Conversion

Z Liu, F Zhang, N Rui, X Li, L Lin, LE Betancourt… - Acs …, 2019 - ACS Publications
The metal–oxide interaction changes the surface electronic states of catalysts deployed for
chemical conversion, yet details of its influence on the catalytic performance under reaction …

Direct conversion of methane to methanol on Ni-Ceria surfaces: metal–support interactions and water-enabled catalytic conversion by site blocking

PG Lustemberg, RM Palomino… - Journal of the …, 2018 - ACS Publications
The transformation of methane into methanol or higher alcohols at moderate temperature
and pressure conditions is of great environmental interest and remains a challenge despite …

Modification strategies for enhancing anti-coking of Ni-, Co-based catalysts during ethanol steam reforming: A review

K Shi, X An, X Wu, X Xie - International Journal of Hydrogen Energy, 2022 - Elsevier
Producing hydrogen from ethanol steam reforming (ESR) is a carbon-neutral and
environment-friendly method, which has been expected to gradually reduce excessive …

Low-Temperature Conversion of Methane to Methanol on CeOx/Cu2O Catalysts: Water Controlled Activation of the C–H Bond

Z Zuo, PJ Ramírez, SD Senanayake, P Liu… - Journal of the …, 2016 - ACS Publications
An inverse CeO2/Cu2O/Cu (111) catalyst is able to activate methane at room temperature
producing C, CH x fragments and CO x species on the oxide surface. The addition of water …

Room-Temperature Activation of Methane and Dry Re-forming with CO2 on Ni-CeO2(111) Surfaces: Effect of Ce3+ Sites and Metal–Support Interactions on C–H …

PG Lustemberg, PJ Ramírez, Z Liu, RA Gutierrez… - Acs …, 2016 - ACS Publications
The results of core-level photoemission indicate that Ni-CeO2 (111) surfaces with small or
medium coverages of nickel are able to activate methane at 300 K, producing adsorbed CH …

Co/CeO2 and Ni/CeO2 catalysts for ethanol steam reforming: Effect of the cobalt/nickel dispersion on catalysts properties

M Greluk, W Gac, M Rotko, G Słowik… - Journal of …, 2021 - Elsevier
Abstract The Co/CeO 2 and Ni/CeO 2 catalysts were obtained by impregnation method with
using different active phase precursors, different impregnation solvents and in presence of …

In situ study of low-temperature dry reforming of methane over La2Ce2O7 and LaNiO3 mixed oxides

AP Ramon, X Li, AH Clark, OV Safonova… - Applied Catalysis B …, 2022 - Elsevier
Dry reforming of methane (DRM) is a promising process to generate synthetic gas with a low
H 2/CO ratio. The main issues in DRM are the deposition of carbon over the catalyst and …

Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO 2 (111) catalysts: an in situ study of C–C and O–H bond scission

Z Liu, T Duchoň, H Wang, DC Grinter… - Physical Chemistry …, 2016 - pubs.rsc.org
Ambient-Pressure X-ray Photoelectron Spectroscopy (AP-XPS) and Infrared Reflection
Absorption Spectroscopy (AP-IRRAS) have been used to elucidate the active sites and …