Methanol Synthesis from CO2 Hydrogenation

M Bowker - ChemCatChem, 2019 - Wiley Online Library
In the future we will be phasing out the use of fossil fuels in favour of more sustainable forms
of energy, especially solar derived forms such as hydroelectric, wind and photovoltaic …

Surface chemistry of late transition metal oxides

JF Weaver - Chemical reviews, 2013 - ACS Publications
The surface chemistry of late transition metal oxides is scientifically interesting and can play
a central role in commercial applications of heterogeneous catalysis. The late transition …

Mechanism of Methanol Synthesis on Cu through CO2 and CO Hydrogenation

LC Grabow, M Mavrikakis - Acs Catalysis, 2011 - ACS Publications
We present a comprehensive mean-field microkinetic model for the methanol synthesis and
water-gas-shift (WGS) reactions that includes novel reaction intermediates, such as formic …

Identification of a Facile Pathway for Dioxymethylene Conversion to Formate Catalyzed by Surface Hydroxyl on TiO2-Based Catalyst

X Chen, G He, Y Li, M Chen, X Qin, C Zhang… - ACS Catalysis, 2020 - ACS Publications
Formaldehyde (HCHO) is either a reactant, intermediate, or product in numerous industrial
catalytic reactions; therefore, revealing the full transformation process of HCHO during …

Methanol synthesis and reverse water–gas shift kinetics over Cu (110) model catalysts: structural sensitivity

J Yoshihara, CT Campbell - Journal of Catalysis, 1996 - Elsevier
The kinetics of simultaneous methanol synthesis and reverse water–gas shift from
CO2/H2and CO2/CO/H2mixtures have been measured at low conversions over a clean Cu …

Selective formic acid dehydrogenation on Pt-Cu single-atom alloys

MD Marcinkowski, J Liu, CJ Murphy, ML Liriano… - Acs …, 2017 - ACS Publications
Formic acid is a potential hydrogen storage molecule which dehydrogenates to form CO2
and H2 on metal surfaces. However, it can also decompose via a competing dehydration …

The kinetics and mechanism of methanol synthesis by hydrogenation of CO2 over a Zn-deposited Cu (111) surface

T Fujitani, I Nakamura, T Uchijima, J Nakamura - Surface science, 1997 - Elsevier
The hydrogenation of CO2 over a Zn-deposited Cu (111) surface has been studied using an
X-ray photoelectron spectroscopy (XPS) apparatus combined with a high-pressure flow …

Supramolecular assemblies of trimesic acid on a Cu (100) surface

A Dmitriev, N Lin, J Weckesser, JV Barth… - The Journal of Physical …, 2002 - ACS Publications
The adsorption and supramolecular ordering of trimesic acid (TMA), 1, 3, 5-
benzenetricarboxylic acid C6H3 (COOH) 3, on a Cu (100) surface has been studied in-situ …

Role of the Adsorbed Oxygen Species in the Selective Electrochemical Reduction of CO2 to Alcohols and Carbonyls on Copper Electrodes

CS Le Duff, MJ Lawrence, P Rodriguez - Angewandte Chemie, 2017 - Wiley Online Library
The electrochemical reduction of CO2 into fuels has gained significant attention recently as
source of renewable carbon‐based fuels. The unique high selectivity of copper in the …

A spectroscopic study of the adsorption and reactions of methanol, formaldehyde and methyl formate on clean and oxygenated Cu (110) surfaces

BA Sexton, AE Hughes, NR Avery - Surface science, 1985 - Elsevier
The adsorption and reaction of methanoi (CH3OH), methyl formate (CH3OCHO) and
formaldehyde (H2CO) on clean and oxygen-covered Cu (110) surfaces has been studied …