Two new manganese (II) complexes based on bisaroylhydrazone derivatives:[Mn II (L 1) 2
(NO 3) 2](1) and [Mn II (L 2) 2 (NO 3) 2](2) were synthesized via the reaction of manganese …

In this work, the catalytic activity of core-shell-type polyoxometalate (POM) composites,
comprised from Keggin POMs encapsulated in Mo 72 Fe 30 Keplerate, in the oxidation of …

Understanding the formation mechanism of giant molecular clusters is essential for rational
design and synthesis of cluster-based nanomaterials with required morphologies and …

In Nature, enzymes provide hydrophobic cavities and channels for sequestering small
alkanes or long‐chain alkyl groups from water. Similarly, the porous metal oxide capsule …

The interaction between human serum albumin (HSA) and a series of Zr (IV)-substituted
polyoxometalates (POMs)(Lindqvist type POM ((n Bu4N) 6 [{W5O18Zr (μ-OH)} 2]· 2H2O, Zr2 …

Porous molecular nanocontainers of {Mo132}‐type Keplerates offer unique opportunities to
study a wide variety of relevant phenomena. An impressive example is provided by the …

(4-Alkoxyphenyl)-5-(p-tolyl)-1, 3, 4-thiadiazoles (alkoxy: O (CH2) n H, n= 1–8)(6a–h)(as a
series of 1, 3, 4-thiadiazole derivatives) and their silver (I) complexes: bis (2-(4 …

ABSTRACT In this work, 1, 2-bis [4-(n-alkoxy) benzylidene] hydrazine (n-alkoxy: O (CH2)
nH, n= 11–18 or 20), a symmetrical series of azines (linear compounds with rod-like shape …

Encapsulation behavior, as well as the presence of internal catalytically active sites, has
been spurring the applications of a 3 nm hollow spherical metal oxide cluster {Mo132} as an …

This work deals with the generation of large numbers of active sites and with ensuing
nucleation/growth processes on the inside wall of the cavity of porous nanocapsules of the …