Buchwald-Hartwig reaction: an overview

MM Heravi, Z Kheilkordi, V Zadsirjan, M Heydari… - Journal of …, 2018 - Elsevier
Pd-catalyzed amination reaction of aryl halides has attracted much attention in recent years.
This review underscores selected important recent developments in the catalysis of one of …

Transition-metal-free coupling reactions

CL Sun, ZJ Shi - Chemical reviews, 2014 - ACS Publications
Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

Tackling solubility issues in organic synthesis: solid-state cross-coupling of insoluble aryl halides

T Seo - Palladium-Catalyzed Mechanochemical Cross …, 2024 - Springer
Conventional organic synthesis generally relies on the use of liquid organic solvents to
dissolve the reactants. Therefore, reactions of sparingly soluble or insoluble substrates are …

The hydrophobic effect applied to organic synthesis: recent synthetic chemistry “in water”

BH Lipshutz, S Ghorai… - Chemistry–A European …, 2018 - Wiley Online Library
Recent developments over the past few years in aqueous micellar catalysis are discussed.
Applications to problems in synthesis are highlighted, enabled by the use of surfactants that …

Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners

R Jana, TP Pathak, MS Sigman - Chemical reviews, 2011 - ACS Publications
Transition metal-catalyzed cross-coupling reactions of organic electrophiles and
organometallic reagents have emerged as a tremendously powerful synthetic tool, and the …

Recent developments in Negishi cross-coupling reactions

D Haas, JM Hammann, R Greiner, P Knochel - ACS Catalysis, 2016 - ACS Publications
This Perspective describes general methods for the preparation of polyfunctional zinc
organometallics and their use in Negishi cross-coupling reactions. Recent advances …

The development of bulky palladium NHC complexes for the most‐challenging cross‐coupling reactions

C Valente, S Çalimsiz, KH Hoi, D Mallik… - Angewandte Chemie …, 2012 - Wiley Online Library
Palladium‐catalyzed cross‐coupling reactions enable organic chemists to form C C bonds
in targeted positions and under mild conditions. Although phosphine ligands have been …

Boron science

NS Hosmane - New technologies and applications, 2011 - api.taylorfrancis.com
What is boron? The question itself may not seem very significant to many people. Their
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …

Palladium-catalyzed Suzuki− Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands

R Martin, SL Buchwald - Accounts of chemical research, 2008 - ACS Publications
The cores of many types of polymers, ligands, natural products, and pharmaceuticals
contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these …

Biaryl phosphane ligands in palladium‐catalyzed amination

DS Surry, SL Buchwald - Angewandte Chemie International …, 2008 - Wiley Online Library
Palladium‐catalyzed amination reactions of aryl halides have undergone rapid development
in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl …