Recent progress of direct thiocyanation reactions

H Chen, X Shi, X Liu, L Zhao - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
Thiocyanates are common in natural products, synthetic drugs and bioactive molecules.
Many thiocyanate derivatives show excellent antibacterial, antiparasitic and anticancer …

Electrochemical difunctionalization of alkenes and alkynes for the synthesis of organochalcogens involving C–S/Se bond formation

J Liu, JP Wan, Y Liu - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
Organochalcogen compounds containing C–S/Se bond are motifs frequently found in
various natural products, bioactive compounds, as well as functional materials. On the other …

Photocatalyst-free visible-light-mediated three-component reaction of α-diazoesters, cyclic ethers and NaSCN to access organic thiocyanates

Z Wang, N Meng, Y Lv, W Wei, H Yue, G Zhong - Chinese Chemical Letters, 2023 - Elsevier
A facile and environmentally friendly visible-light-induced three-component reaction of α-
diazoesters, cyclic ethers and NaSCN to construct organic thiocyanates has been …

External electrolyte-free electrochemical one-pot cascade synthesis of 4-thiocyanato-1H-pyrazoles

WB He, SJ Zhao, JY Chen, J Jiang, X Chen, X Xu… - Chinese Chemical …, 2023 - Elsevier
ABSTRACT A practical synthetic method for 4-thiocyanato-1H-pyrazoles through the
electrochemical cascade reaction of hydrazines, 1, 3-diones and NH 4 SCN under metal …

Design and Use of Electrophilic Thiocyanating and Selenocyanating Reagents: An Interesting Trend for the Construction of SCN‐and SeCN‐Containing Compounds

M Gao, M Vuagnat, MY Chen… - … A European Journal, 2021 - Wiley Online Library
Organothiocyanate and organoselenocyanate compounds are of paramount importance in
organic chemistry as they are key intermediates to access sulfur‐and selenium‐containing …

Electrochemical oxidative thiocyanation and amination of enaminones towards the synthesis of multi-substituted alkenes

F Lu, K Zhang, Y Yao, Y Yin, J Chen, X Zhang… - Green …, 2021 - pubs.rsc.org
A highly stereoselective synthesis of thiocyanated enaminones was achieved by an
electrochemical process, which involved C–H bond thiocyanation and vinyl C–N bond …

AIBN-initiated direct thiocyanation of benzylic sp 3 C–H with N-thiocyanatosaccharin

D Wu, Y Duan, K Liang, H Yin, FX Chen - Chemical Communications, 2021 - pubs.rsc.org
Direct thiocyanations of benzylic compounds have been implemented. Here, a new strategy,
involving a free radical reaction pathway initiated by AIBN, was used to construct the …

An electrochemical method for deborylative seleno/thiocyanation of arylboronic acids under catalyst-and oxidant-free conditions

D He, J Yao, B Ma, J Wei, G Hao, X Tuo, S Guo, Z Fu… - Green …, 2020 - pubs.rsc.org
An electrochemical deborylative seleno/thiocyanation of arylboronic acids has been well
established to synthesize the corresponding aryl seleno/thiocyanates with good functional …

Elemental sulfur as the “S” source: visible-light-mediated four-component reactions leading to thiocyanates

Z Wang, R Liu, C Qu, XE Zhao, Y Lv, H Yue… - Organic Chemistry …, 2022 - pubs.rsc.org
An eco-friendly and photocatalyst-free visible-light-promoted four-component reaction of α-
diazoesters, elemental sulfur, cyclic ethers and TMSCN is described. A series of diverse …

Lewis-acid-mediated thiocyano semipinacol rearrangement of allylic alcohols for construction of α-quaternary center β-thiocyano carbonyls

XF Song, AH Ye, YY Xie, JW Dong, C Chen… - Organic …, 2019 - ACS Publications
An electrophilic thiocyano semipinacol rearrangement of allylic alcohols has been achieved
for the first time by using N-thiocyano-dibenzenesulfonimide (NTSI). This approach provides …