The interest in functional supramolecular systems for the design of innovative materials and
technologies, able to fundamentally change the world, is growing at a high pace. The huge …

Polyoxometalate (POM) compounds constitute a wide family rich of more than several
thousand inorganic compounds which can be finely tuned at the molecular level …

In this communication, we report on a noteworthy hybrid supramolecular assembly built from
three functional components hierarchically organized through noncovalent interactions. The …

In this work, the catalytic activity of core-shell-type polyoxometalate (POM) composites,
comprised from Keggin POMs encapsulated in Mo 72 Fe 30 Keplerate, in the oxidation of …

Polyoxopalladates (POPs) are a class of self‐assembling palladium‐oxide clusters that span
a variety of sizes, shapes and compositions. The largest of this family,{Pd84} Ac, is …

The effectiveness of the interactions between various alkylammonium cations and the well-
defined spherical Keplerate-type {Mo132} capsule has been tracked by 1H DOSY NMR …

Despite the proliferation of tungstate and molybdate polyoxometalates (POMs) the inclusion
of sulfides into these structures proved to be challenging. The use of appropriate preformed …

The internal functionalization of the Keplerate‐type capsule Mo132 has been carried out by
ligand exchange leading to the formation of glutarate and succinate containing species …

This paper deals with the electrochemical studies performed in DMF on three iso-electronic
compounds of general formula γ-[SiW10O36 (M2O2E2)] 6−, which differ either with respect …

Two dimethyldioctadecylammonium (DODA+) salts of a new keplerate with the general
formula [Mo132O312S60 (SO4) x (H2O) 132–2 x](12+ 2 x)− and abbreviated DODA n …