Transition-metal-catalyzed, coordination-assisted C (sp3)–H functionalization has
revolutionized synthetic planning over the past few decades as the use of these directing …

The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Computational studies on carboxylate-assisted C–H activation and functionalization at
group 8–10 transition metal centers are reviewed. This Review is organized by metal and …

Palladium-catalyzed C H activation/C O bond-forming reactions have emerged as
attractive tools for organic synthesis. Typically, these reactions require strong chemical …

Synthetic organic chemistry has witnessed a plethora of functionalization and
defunctionalization strategies. In this regard, C− H functionalization has been at the forefront …

Abstract Oxidative C (sp 3)–H bond functionalization is a powerful tool in organic synthesis,
but the stoichiometric oxidants required for bond formation raise environmental concerns …

A silver-and copper-free rhodium-catalyzed C–H acetoxylation reaction of azaindoles has
been achieved at near ambient temperature employing PIDA as a nonmetallic acetoxy …

Rh (III)-Catalyzed highly regioselective direct acyloxylation of sp2 C–H bonds with
carboxylic acids has been developed. The catalytic system consisting of a cationic Rh (III) …

Bidentate directing group (DG) strategy is a promising way to achieve sp2 and more inert
sp3 C–H bond activations in transition metal (TM) catalysis. In this work, we systematically …

Quantum chemical reaction path finding methods are herein used to investigate the
mechanism of Pd-catalyzed distal functionalization of piperidine, as reported by Sanford …