Characterization, Structure, and Reactivity of Hydroxyl Groups on Metal‐Oxide Cluster Nodes of Metal–Organic Frameworks: Structural Diversity and Keys to …

D Yang, BC Gates - Advanced Materials, 2024 - Wiley Online Library
Among the most stable metal–organic frameworks (MOFs) are those incorporating nodes
that are metal oxide clusters with frames such as Zr6O8. This review is a summary of the …

Stability and hydrolyzation of metal organic frameworks with paddle-wheel SBUs upon hydration

K Tan, N Nijem, P Canepa, Q Gong, J Li… - Chemistry of …, 2012 - ACS Publications
Instability of most prototypical metal organic frameworks (MOFs) in the presence of moisture
is always a limitation for industrial scale development. In this work, we examine the …

Phase transition enthalpy measurements of organic and organometallic compounds. Sublimation, vaporization and fusion enthalpies from 1880 to 2015. Part 1. C1 …

W Acree, JS Chickos - Journal of Physical and Chemical Reference …, 2016 - pubs.aip.org
A compendium of phase change enthalpies published in 2010 is updated to include the
period 1880–2015. Phase change enthalpies including fusion, vaporization, and …

Tuning Catalytic Sites on Zr6O8 Metal–Organic Framework Nodes via Ligand and Defect Chemistry Probed with tert-Butyl Alcohol Dehydration to Isobutylene

D Yang, CA Gaggioli, D Ray, M Babucci… - Journal of the …, 2020 - ACS Publications
Metal–organic frameworks (MOFs) have drawn wide attention as candidate catalysts, but
some essential questions about their nature and performance have barely been …

Adsorption and Immobilization of Cytochrome c on Nanodiamonds

LCL Huang, HC Chang - Langmuir, 2004 - ACS Publications
Methods have been developed to immobilize proteins onto the surfaces of nanodiamonds
with an average size of 5±1 nm. The immobilization started with carboxylation/oxidization of …

Water interactions in metal organic frameworks

K Tan, N Nijem, Y Gao, S Zuluaga, J Li… - …, 2015 - pubs.rsc.org
Metal organic frameworks (MOFs) have a strong potential for gas adsorption and separation
such as H2 and CH4 storage, and CO2 capture. However, their instability in the presence of …

Matrix-isolation infrared and theoretical studies of the glycine conformers

SG Stepanian, ID Reva, ED Radchenko… - The Journal of …, 1998 - ACS Publications
The IR spectra of nonionized glycine and its deuterated derivatives isolated in the low-
temperature argon matrices have been measured, and for the first time the infrared spectral …

Theoretical modeling of the OH stretch infrared spectrum of carboxylic acid dimers based on first-principles anharmonic couplings

GM Florio, TS Zwier, EM Myshakin… - The Journal of …, 2003 - pubs.aip.org
Carboxylic acid dimers serve as prototypical systems for modeling the unusual spectral
behavior of the hydride stretch fundamental. Large anharmonic effects associated with the …

On the electrocatalytically active sites in graphene-based vanadium redox flow batteries

RM Bachman, DM Hall, LR Radovic - Carbon, 2023 - Elsevier
There is too much controversy and too little interdisciplinary analysis of the role of carbon
electrodes in a wide range of electrochemical and electrocatalytic processes. Here we focus …

Determination of noncovalent docking by infrared spectroscopy of cold gas-phase complexes

E Garand, MZ Kamrath, PA Jordan, AB Wolk… - Science, 2012 - science.org
Multidentate, noncovalent interactions between small molecules and biopolymer fragments
are central to processes ranging from drug action to selective catalysis. We present a …