Metal‐organic frameworks (MOFs) show potential application in many domains, in which
photochromic MOFs (PMOFs) have received enormous attention. Researchers mainly utilize …

1, 10-Phenanthroline (phen) is one of the most popular ligands ever used in coordination
chemistry due to its strong affinity for a wide range of metals with various oxidation states. Its …

The synthesis and solution and solid-state characterization of [Pu4+ (NPC) 4], 1-
Pu,(NPC=[NP t Bu (pyrr) 2]−; t Bu= C (CH3) 3; pyrr= pyrrolidinyl) and [Pu3+ (NPC) 4][K (2.2 …

Variations in bonding between trivalent lanthanides and actinides is critical for reprocessing
spent nuclear fuel. The ability to tune bonding and the coordination environment in these …

The complexation of selected trivalent lanthanide ions with derivatives of the tetranitrogen
donor ligands 6, 6′-bis-1R, 1 H-1, 2, 3-triazol-4-yl-2, 2′-bipyridines (BTzBPs, R= alkyl or …

The reaction of 249Bk (OH) 4 with iodate under hydrothermal conditions results in the
formation of Bk (IO3) 3 as the major product with trace amounts of Bk (IO3) 4 also …

Local conditions, such as temperature and oxygen availability, have a pronounced effect on
the formation and evolution of fallout following a nuclear explosion. While the behavior of …

A cerium–oxo nanocluster capped by chloride ligands,[CeIV38–n CeIII n O56–(n+ 1)(OH) n+
1Cl51 (H2O) 11] 10–(n= 1–24), has been isolated from acidic chloride solutions by using …

Small-scale reactions of the Pu analogues La, Ce, and Nd have been explored in order to
optimize reaction conditions for milligram scale reactions of radioactive plutonium starting …

A series of eighteen tetravalent actinide (An= Th, U, Pu) compounds were synthesized from
acidic aqueous solutions containing thorium, uranium, or plutonium and a series of …