Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …

Porphyrin arrays are an important class of compounds to study interporphyrin electronic
interactions that are crucial in determining the rates of energy transfer and electron transfer …

Utilizing nonplanar conjugated molecules as building blocks facilitates the development of
self-assembly but is fundamentally challenging. To study the self-assembly behavior, we …

Sapphyrin is a pentapyrrolic expanded porphyrin with a 22π aromatic character. Herein, we
report the synthesis of a 20π antiaromatic sapphyrin isomer 1 by oxidative cyclization of a …

Carbaporphyrin dimers, investigated for their distinctive electronic structures and
exceptional properties, have predominantly consisted of systems containing identical …

Porphyrin dimers have been widely explored and studied owing to their importance in
photosynthetic systems. A vast variety of dimers linked by different groups and at different …

Rational synthesis, spectroscopic and solid-state structural isolation of an unprecedented
core modified N-confused fused porphyrinogen 7 as a single isomer has been achieved in …

Developing artificial enzymes based on organic molecules or polymers for reactive oxygen
biocatalysis has broad applicability. Here, inspired by heme-based enzyme systems, we …

Dimesitylorangarin and its BF2 complex were synthesized by double SNAr reaction of 3, 5‐
dibromo‐BODIPY with 2‐pyrrolydipyrrin as the first examples of meso‐aryl‐substituted …

A quinoxaline-fused octaphyrin (2.0. 0.0. 2.0. 0.0) was synthesized by the FeCl3-induced
oxidative coupling of an α-free quinoxaline-fused tetrapyrrole. This macrocycle adopts a …