According to the CRC dictionary of natural products, 1 90% of chemically individual
molecules discovered in nature contain either a carbocyclic or a heterocyclic subunit. 2 Not …

Free radical cyclization of enantiomerically pure, acyclic presursors derived from
carbohydrates is an excellent method for the synthesis of complex, densely functionalized …

The free radical cyclization (FR) and the ring-closing metathesis (RCM) reaction have been
analyzed in order to develop new and original synthetic protocols for the synthesis of …

An efficient radical sequence involving a 5-exo-dig, a diastereoselective 1, 5-H transfer, and
a rarely observed in an all-carbon system 5-endo-trig cyclization allows the construction of …

A total synthesis of (+)-goniothalesdiol, a 3, 4-dihydroxy-2, 5-disubstituted tetrahydrofuran
isolated from Goniothalamus borneensis (Annonaceae), and its 7-epimer is reported using …

In this work, we have shown that the tributyltin hydride-mediated cycloisomerization of allene-
tethered oxime ethers or hydrazones is a convenient method for the preparation of …

The synthesis of compounds 6-8, derived from 2, 3: 5, 6-bis-O-isopropylidene-d-
mannofuranose (3), and the preparation of products 16 and 17, obtained from 2, 3-O …

A formal and improved synthesis of natural (+)-varitriol from d-glucose and dimethyl l-
tartrate, respectively, are reported. The key steps are the Pd (II)/Cu (II)-catalysed …

Synthesis of chiral, densely functionalized medium-sized rings from carbohydrate precursors
via regioselective exo/endo-primary alkyl radical cyclizations - ScienceDirect Skip to main …

Sequential, radical-mediated cyclizations of 1, 5-enynes have been evaluated with respect
to structure, stereochemistry and reactivity. In series A 5-exo-trig, 6-endo-dig cascades are …