Recent advances in radical C–H activation/radical cross-coupling

H Yi, G Zhang, H Wang, Z Huang, J Wang… - Chemical …, 2017 - ACS Publications
Research and industrial interest in radical C–H activation/radical cross-coupling chemistry
has continuously grown over the past few decades. These reactions offer fascinating and …

Syntheses and transformations of sulfoximines

W Zheng, X Chen, F Chen, Z He… - The Chemical Record, 2021 - Wiley Online Library
Sulfoximines are widely used as medicines, agricultural chemicals, chiral precursors, and
chiral ligands in asymmetric synthesis, as well as pivotal intermediates for the construction of …

A Counterion/Ligand-Tuned Chemo-and Enantioselective Copper-Catalyzed Intermolecular Radical 1, 2-Carboamination of Alkenes

XY Cheng, YF Zhang, JH Wang, QS Gu… - Journal of the …, 2022 - ACS Publications
The copper-catalyzed enantioselective intermolecular radical 1, 2-carboamination of
alkenes with readily accessible alkyl halides is an appealing strategy for producing chiral …

Copper‐Catalyzed Enantioconvergent Radical C(sp3)−N Cross‐Coupling: Access to α,α‐Disubstituted Amino Acids

YF Zhang, JH Wang, NY Yang, Z Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
Transition‐metal catalyzed enantioconvergent cross‐coupling of tertiary alkyl halides with
ammonia offers a rapid avenue to chiral unnatural α, α‐disubstituted amino acids. However …

N− H and C− H functionalization of sulfoximine: recent advancement and prospects

P Ghosh, B Ganguly, S Das - Asian Journal of Organic …, 2020 - Wiley Online Library
Sulfoximine and its congeners are a versatile class of structural motifs widely found in a
plethora of pharmaceutical compounds and crop protection industries due to their …

Nickel‐Catalyzed Dehydrogenative Cross‐Coupling: Direct Transformation of Aldehydes into Esters and Amides

AM Whittaker, VM Dong - Angewandte Chemie International …, 2015 - Wiley Online Library
By exploring a new mode of nickel‐catalyzed cross‐coupling, a method to directly transform
both aromatic and aliphatic aldehydes into either esters or amides has been developed. The …

Electrochemical Oxidative Carbonylation of NH-Sulfoximines

M Li, M Peng, W Huang, L Zhao, S Wang, C Kang… - Organic …, 2023 - ACS Publications
The electrochemical synthesis of N-aroylsulfoximines features the use of tetra-n-
butylammonium iodide (TBAI) as the medium and a broad substrate scope, thus affording a …

Iron-Catalyzed Hetero-Cross-Dehydrogenative Coupling Reactions of Sulfoximines with Diarylmethanes: A New Route to N-Alkylated Sulfoximines

Y Cheng, W Dong, L Wang, K Parthasarathy… - Organic letters, 2014 - ACS Publications
An efficient iron-catalyzed C–N bond formation by hetero-cross-dehydrogenative coupling
(CDC) between sulfoximines and diarylmethanes is described. The reaction shows good …

Synthesis of sulfoximine carbamates by rhodium-catalyzed nitrene transfer of carbamates to sulfoxides

M Zenzola, R Doran, R Luisi, JA Bull - The Journal of Organic …, 2015 - ACS Publications
Sulfoximines are of considerable interest for incorporation into medicinal compounds. A
convenient synthesis of N-protected sulfoximines is achieved, under mild conditions, by …

Rhodium(III)‐Catalyzed Selective ortho‐Olefinations of N‐Acyl and N‐Aroyl Sulfoximines by CH Bond Activation

K Parthasarathy, C Bolm - Chemistry–A European Journal, 2014 - Wiley Online Library
Two new rhodium‐catalyzed oxidative couplings between sulfoximine derivatives and
alkenes by regioselective C H activation, affording ortho‐olefinated (Heck‐type) products …