Metal–organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal …

TR Cook, YR Zheng, PJ Stang - Chemical reviews, 2013 - ACS Publications
In 1893, Alfred Werner described the structure of octahedral transition metal complexes and
provided the basis for assigning coordination number and oxidation state to what were then …

Towards artificial molecular factories from framework-embedded molecular machines

S Krause, BL Feringa - Nature Reviews Chemistry, 2020 - nature.com
Controlling cooperativity, synchronization, amplification and translation of intermolecular
and intramolecular dynamics over different length scales for applications in stimuli …

Supramolecular ferroelectrics

AS Tayi, A Kaeser, M Matsumoto, T Aida, SI Stupp - Nature Chemistry, 2015 - nature.com
Supramolecular chemistry uses non-covalent interactions to coax molecules into forming
ordered assemblies. The construction of ordered materials with these reversible bonds has …

Soft porous crystals

S Horike, S Shimomura, S Kitagawa - Nature chemistry, 2009 - nature.com
The field of host–guest complexation is intensely attractive from diverse perspectives,
including materials science, chemistry and biology. The uptake and encapsulation of guest …

Tunable and switchable dielectric constant in an amphidynamic crystal

W Zhang, HY Ye, R Graf, HW Spiess… - Journal of the …, 2013 - ACS Publications
The inclusion compound [(CH3) 2NH2] 2 [KCo (CN) 6] exhibits a marked temperature-
dependent dielectric constant and can be considered as a model of tunable and switchable …

Crystalline molecular machines: function, phase order, dimensionality, and composition

CS Vogelsberg, MA Garcia-Garibay - Chemical Society Reviews, 2012 - pubs.rsc.org
The design of molecular machines is stimulated by the possibility of developing new
materials with complex physicochemical and mechanical properties that are responsive to …

Phenyl ring dynamics in a tetraphenylethylene-bridged metal–organic framework: implications for the mechanism of aggregation-induced emission

NB Shustova, TC Ong, AF Cozzolino… - Journal of the …, 2012 - ACS Publications
Molecules that exhibit emission in the solid state, especially those known as aggregation-
induced emission (AIE) chromophores, have found applications in areas as varied as light …

An adaptable peptide-based porous material

J Rabone, YF Yue, SY Chong, KC Stylianou, J Bacsa… - Science, 2010 - science.org
Porous materials find widespread application in storage, separation, and catalytic
technologies. We report a crystalline porous solid with adaptable porosity, in which a simple …

Controlling dynamics in extended molecular frameworks

L Feng, RD Astumian, JF Stoddart - Nature Reviews Chemistry, 2022 - nature.com
Molecular machines are essential dynamic components for fuel production, cargo delivery,
information storage and processing in living systems. Scientists have demonstrated that they …

Biologically derived metal organic frameworks

SL Anderson, KC Stylianou - Coordination Chemistry Reviews, 2017 - Elsevier
Metal organic frameworks (MOFs) are extended structures composed of a network of organic
ligands and metal ions or clusters connected to each other via coordination bonds. The …