Halogenation is one of the most important transformations in organic synthesis.
Halogenated compounds are employed in many reactions to prepare useful molecules …

Herein, we disclose the first report on gold‐catalyzed C (sp2)‐CN cross‐coupling reaction
by employing a ligand‐enabled Au (I)/Au (III) redox catalysis. This transformation utilizes …

Compared to the well-established transition metal-catalyzed cross-coupling reactions, Au
(I)/Au (III)-catalyzed cross-coupling reactions have lagged behind. Despite some …

Transition metal‐catalyzed Suzuki and Heck reactions are two of the most common carbon‐
carbon bond formation reactions. Gold, unlike other transition metals (Pd, Ni, and Cu), offers …

Cope rearrangements have garnered significant attention owing to their ability to undergo
structural reorganization in stereoselective manner. While substantial advances have been …

Two recent high‐profile publications reported the formation of Heck‐type arylated alkenes
catalysed by MeDalPhosAuCl/AgOTf (J. Am. Chem. Soc. 2023, 145, 8810) and their …

A gold-catalyzed C (sp3)–C (sp2) Suzuki–Miyaura coupling reaction facilitated by ligand-
enabled Au (I)/Au (III) redox catalysis was developed. The cross-coupling of alkyl …

A gold-catalyzed sulfonylation reaction of aryl iodides with different sodium sulfinates
facilitated by the ligand-enabled Au (I)/Au (III) redox catalysis was developed. In the reaction …

In zwei vielbeachteten Veröffentlichungen wurde vor kurzem über die Bildung von arylierten
Heck‐Olefinen durch Katalyse mit MeDalPhosAuCl/AgOTf (J. Am. Chem. Soc. 2023, 145 …

A gold-catalyzed sulfonylation of aryl/vinyl iodides to synthesize aryl sulfones facilitated by
the ligand-enabled Au (I)/Au (III) redox catalysis was developed. In the reaction, aryl sodium …