The progress and outlook of metal single-atom-site catalysis

X Liang, N Fu, S Yao, Z Li, Y Li - Journal of the American Chemical …, 2022 - ACS Publications
Single-atom-site catalysts (SASCs) featuring maximized atom utilization and isolated active
sites have progressed tremendously in recent years as a highly prosperous branch of …

Challenges and opportunities in engineering the electronic structure of single-atom catalysts

V Giulimondi, S Mitchell, J Pérez-Ramírez - ACS catalysis, 2023 - ACS Publications
Controlling the electronic structure of transition-metal single-atom heterogeneous catalysts
(SACs) is crucial to unlocking their full potential. The ability to do this with increasing …

Coordination modulation of iridium single-atom catalyst maximizing water oxidation activity

Z Lei, W Cai, Y Rao, K Wang, Y Jiang, Y Liu… - Nature …, 2022 - nature.com
Single-atom catalysts (SACs) have attracted tremendous research interests in various
energy-related fields because of their high activity, selectivity and 100% atom utilization …

Understanding synthesis–structure–performance correlations of nanoarchitectured activated carbons for electrochemical applications and carbon capture

S Zhang, M Zheng, Y Tang, R Zang… - Advanced Functional …, 2022 - Wiley Online Library
Activated carbons are one of the most important classes of high‐surface‐area porous
materials. Owing to their unique structure, low price, and large‐scale production technology …

Performance descriptors of nanostructured metal catalysts for acetylene hydrochlorination

SK Kaiser, E Fako, I Surin, F Krumeich… - Nature …, 2022 - nature.com
Controlling the precise atomic architecture of supported metals is central to optimizing their
catalytic performance, as recently exemplified for nanostructured platinum and ruthenium …

Tailoring asymmetric Cu-OP coupling site by carbothermal shock method for efficient vinyl chloride synthesis over carbon supported Cu catalysts

Y Yue, S Wang, Q Zhou, B Wang, C Jin, R Chang… - ACS …, 2023 - ACS Publications
It remains challenging to achieve nanoparticles with uniform size and dispersion or single
atoms with identical coordination structure, although various methods have been developed …

Asymmetric Ru-In atomic pairs promote highly active and stable acetylene hydrochlorination

Y Fan, H Xu, G Gao, M Wang, W Huang, L Ma… - Nature …, 2024 - nature.com
Ru single-atom catalysts have great potential to replace toxic mercuric chloride in acetylene
hydrochlorination. However, long-term catalytic stability remains a grand challenge due to …

Reaction‐Induced Formation of Stable Mononuclear Cu (I) Cl Species on Carbon for Low‐Footprint Vinyl Chloride Production

D Faust Akl, G Giannakakis… - Advanced …, 2023 - Wiley Online Library
Copper catalysts are attractive candidates for Hg‐free vinyl chloride monomer (VCM)
production via acetylene hydrochlorination due to their non‐toxic nature and high stability …

Oxygen-doped carbon supports modulate the hydrogenation activity of palladium nanoparticles through electronic metal–support interactions

RG Rao, R Blume, MT Greiner, P Liu, TW Hansen… - ACS …, 2022 - ACS Publications
In heterogeneous catalysis, synergies between the metal active phase and oxide support
can enhance the catalytic activity through electronic metal–support interactions (EMSI). Such …

Evidence of bifunctionality of carbons and metal atoms in catalyzed acetylene hydrochlorination

V Giulimondi, A Ruiz-Ferrando, G Giannakakis… - Nature …, 2023 - nature.com
Carbon supports are ubiquitous components of heterogeneous catalysts for acetylene
hydrochlorination to vinyl chloride, from commercial mercury-based systems to more …