[HTML][HTML] Electronic spectroscopy of the A1̃2A′′/A2̃2A′− X̃2A′ transitions of jet-cooled calcium ethoxide radicals: Vibronic structure of alkaline earth monoalkoxide …

AC Paul, K Sharma, H Telfah, TA Miller… - The Journal of Chemical …, 2021 - pubs.aip.org
Laser-induced fluorescence/dispersed fluorescence (LIF/DF) and cavity ring-down spectra
of the A 1 ̃ 2 A′′/A 2 ̃ 2 A′− X ̃ 2 A′ electronic transition of the calcium ethoxide (CaOC 2 …

A combined experimental and computational study on the transition of the calcium isopropoxide radical as a candidate for direct laser cooling

H Telfah, K Sharma, AC Paul, SMS Riyadh… - Physical Chemistry …, 2022 - pubs.rsc.org
Vibronically resolved laser-induced fluorescence/dispersed fluorescence (LIF/DF) and cavity
ring-down (CRD) spectra of the electronic transition of the calcium isopropoxide [CaOCH …

Jet-cooled laser-induced fluorescence spectroscopy of cyclohexoxy: Rotational and fine structure of molecules in nearly degenerate electronic states

J Liu, TA Miller - The Journal of Physical Chemistry A, 2014 - ACS Publications
The rotational structure of the previously observed B̃ 2A′← X̃ 2A ″and B̃ 2A′← Ã 2A′
laser-induced fluorescence spectra of jet-cooled cyclohexoxy radical (c-C6H11O)[Zu, L.; Liu …

Unified Description of the Jahn–Teller Effect in Molecules with Only Cs Symmetry: Cyclohexoxy in Its Full 48-Dimensional Internal Coordinates

Y Shen, DR Yarkony - The Journal of Physical Chemistry A, 2021 - ACS Publications
The two lowest potential energy surfaces of cyclohexoxy which are coupled by conical
intersections and the spin–orbit interaction are determined in the full 48-dimensional internal …

[HTML][HTML] Rotational and fine structure of open-shell molecules in nearly degenerate electronic states

J Liu - The Journal of Chemical Physics, 2018 - pubs.aip.org
An effective Hamiltonian without symmetry restriction has been developed to model the
rotational and fine structure of two nearly degenerate electronic states of an open-shell …

Laser-Induced Fluorescence Spectroscopy of Large Secondary Alkoxy Radicals: Part I. Spectral Overviews and Vibronic Analysis

J Liu, TA Miller - The Journal of Physical Chemistry A, 2021 - ACS Publications
We report vibronically resolved laser-induced fluorescence (LIF) spectra of jet-cooled C5–
C10 secondary alkoxy radicals. The LIF spectra demonstrate vibronic structures similar to …

[HTML][HTML] Rotational and fine structure of open-shell molecules in nearly degenerate electronic states. II. Interpretation of experimentally determined interstate coupling …

Y Yan, K Sharma, TA Miller, J Liu - The Journal of Chemical Physics, 2020 - pubs.aip.org
Rotationally and fine-structure resolved B ̃← X ̃ laser-induced fluorescence (LIF) spectra of
alkoxy radicals have been simulated with a “coupled two-states model”[J. Liu, J. Chem …

Dispersed fluorescence spectroscopy of jet-cooled 2-, 3-, and 4-methylcyclohexoxy radicals

J Alam, MA Reza, A Mason, NJ Reilly… - The Journal of Physical …, 2015 - ACS Publications
Vibrational structures of the nearly degenerate X̃ and à states of the 2-, 3-, and 4-
methylcyclohexoxy (MCHO) radicals were studied by jet-cooled dispersed fluorescence (DF) …

Laser-Induced Fluorescence Spectroscopy of Large Secondary Alkoxy Radicals: Part II. Rotational and Fine Structure

J Liu, MW Chen, TA Miller - The Journal of Physical Chemistry A, 2021 - ACS Publications
Selected vibronic bands of the B̃← X̃ laser-induced fluorescence (LIF) spectra of jet-cooled 2-
pentoxy and 2-hexoxy, including the origin and CO-stretch bands, have been measured with …

Revealing Long-Range Substituent Effects in the Laser-Induced Fluorescence and Dispersed Fluorescence Spectra of Jet-Cooled CHxF3–xCH2O (x = 1, 2, 3) …

B Koncz, G Bazsó, MA Reza, H Telfah… - The Journal of …, 2019 - ACS Publications
The B̃–X̃ laser-induced fluorescence (LIF) and dispersed fluorescence (DF) spectra of the
atmospherically important β-monofluoro ethoxy (MFEO), β, β-difluoro ethoxy (DFEO), and β …