A review on the aqueous chemistry of Zr (IV) and Hf (IV) and their separation by solvent extraction

LY Wang, MS Lee - Journal of Industrial and Engineering Chemistry, 2016 - Elsevier
Solvent extraction systems for the separation of zirconium (IV) and hafnium (IV) from different
aqueous media, such as sulfate, chloride and nitrate were reviewed. The important …

Solvent extraction for the separation of Zr and Hf from aqueous solutions

R Banda, MS Lee - Separation & Purification Reviews, 2015 - Taylor & Francis
The present review mainly focused on the recent extraction and separation studies of Zr and
Hf from various acidic aqueous solutions using liquid-liquid extraction. The general purpose …

Investigation of experimental results and D-optimal design of hafnium ion extraction from aqueous system using emulsion liquid membrane technique

I Salahshoori, A Hatami, A Seyfaee - Journal of the Iranian Chemical …, 2021 - Springer
Hafnium metal is used in a wide range of industries such as microprocessor manufacturing,
nuclear reactors and special alloys due to its physical, chemical and radiation properties …

Separation of zirconium from hafnium in sulfate medium using solvent extraction with a new reagent BEAP

S Chen, Z Zhang, S Kuang, Y Li, X Huang, W Liao - Hydrometallurgy, 2017 - Elsevier
Abstract A new extractant, bis (2-ethylhexyl)-1-(2-ethylhexylamino) propylphosphonate
(BEAP or B) was synthesized to extract and separate zirconium and hafnium from sulfate …

Separation of hafnium from zirconium in HNO3 solution by solvent extraction with Cyanex572

H He, F Xu, Q Li, P Dong, J Zheng, C Wu, Z He, J Qu… - Hydrometallurgy, 2021 - Elsevier
Extraction and separation of hafnium (Hf) from zirconium (Zr) in HNO 3 solution were carried
out with Cyanex572 as extractant. Hf could be selectively extracted with an optimized …

Separation of Zr from Hf in hydrochloric acid solution using amine-based extractants

R Banda, HY Lee, MS Lee - Industrial & engineering chemistry …, 2012 - ACS Publications
Liquid–liquid extraction studies have been performed to investigate the selective extraction
of zirconium (Zr) and hafnium (Hf) in hydrochloric acid medium. For this purpose, several …

Solvent extraction separation of zirconium and hafnium from nitric acid solutions using mixture of Cyanex-272 and TBP

A Yadollahi, K Saberyan, M Torab-Mostaedi… - Radiochimica …, 2018 - degruyter.com
A solvent extraction method has been employed to extract and separate zirconium and
hafnium from the nitric acid medium using Cyanex-272 and its mixture with TBP in kerosene …

Enhanced adsorption and separation of zirconium and hafnium under mild conditions by phosphoric acid based ligand functionalized silica gels: Insights from …

A Das, KRS Chandrakumar, B Paul… - Separation and …, 2020 - Elsevier
Separation of zirconium and hafnium is one of the challenging problems due to their similar
chemical behaviors and in general, their separation has been carried out under very high …

Separation of hafnium from zircon leach solution using anion-exchange resin and production of high-purity zirconia for nuclear applications

ZH Ismail, SE Rizk, EMA Elgoud, HF Aly - Hydrometallurgy, 2025 - Elsevier
The ion exchange process using an anion exchange resin (Bio-Rex 5) was employed with
batch and column techniques to isolate nuclear-grade zirconium/hafnium from a leach …

Extraction of molybdenum (VI) from nitric acid medium and its recovery from Gattar granite ore using CYANEX 923 in kerosene

MM Zeid, BA Masry, AT Kassem, HG Noweir, EA Saad… - Hydrometallurgy, 2018 - Elsevier
This paper describes the extraction of molybdenum (VI) from aqueous nitric acid solution by
trialkylphosphine oxide (CYANEX 923) in kerosene as diluent with 15%(v/v) cyclohexane as …