The interaction of organic azides with transition metal complexes will be discussed with
particular attention to the coordination modes of these molecules. The stoichiometric …

Characterizing reactive organometallic intermediates is critical for understanding the
mechanistic aspects of metal-mediated organic reactions. Moreover, the isolation of reactive …

Two series of Schiff base metal complexes were investigated, where each series was
supported by an ancillary ligand incorporating a ferrocene backbone and different N= X …

The coupling of tertiary phosphines and azides, commonly referred to as the Staudinger
reaction (Scheme 1), provides a straightforward route to phosphazenes.[1] Numerous …

Abstract The guanidine 1, 5, 7‐triazabicyclo [4.4. 0] dec‐5‐ene (TBD) and the substituted
derivatives [TBD–SiR2]+ and TBD–BR2 reacted with SO2 to give different FLP–SO2 …

The Staudinger reaction between phosphines and azides provides a straightforward route to
azaylides. Until the 1980s, it was thought that the putative intermediates of this reaction …

o-Carboalkoxy triarylphosphines are shown to react with aryl azides to provide Staudinger
ligation products bearing O-alkyl imidate linkages. This is in contrast to alkyl azides whose …

Abstract The Al-and Ga-based frustrated Lewis pairs (FLPs) Mes2P–C (MR2)= CH-R′(1,
M= Al, R= t Bu; 2, M= Al, R= CH2 t Bu; 3, M= Ga, R= t Bu) and the unique P–H functionalized …

The reactions of triphenylphosphine with the azido-ortho-closo-dicarbadodecaboranes 1-N3-
2-R-closo-1, 2-C2B10H10 [R= Me (1a), Ph (1b)] produce the stable and isolatable …

The reaction of ruthenapentalyne with one equivalent of isocyanide led to the formation of a
rare ruthenapentalene complex by nucleophilic addition. When excess isocyanides were …