Recent advances on the chemistry of transition metal complexes of 2-(arylazo) pyridines and its arylamino derivatives
Recent advancement on the redox properties of a selection of transition metal complexes of
the azoaromatic ligands: bidentate L1 [2-(arylazo) pyridine] and tridentate HL2 [2 …
the azoaromatic ligands: bidentate L1 [2-(arylazo) pyridine] and tridentate HL2 [2 …
Manifestations of noninnocent ligand behavior
W Kaim - Inorganic Chemistry, 2011 - ACS Publications
The potential of redox-active ligands to behave “noninnocently” in transition-metal
coordination compounds is reflected with respect to various aspects and situations. These …
coordination compounds is reflected with respect to various aspects and situations. These …
Azo anion radical complex of rhodium as a molecular memory switching device: isolation, characterization, and evaluation of current–voltage characteristics
Two rare examples of azo anion diradical complexes of Rh (III) are reported. These
complexes showed excellent memory switching properties with a large ON/OFF ratio and …
complexes showed excellent memory switching properties with a large ON/OFF ratio and …
Spectroscopic, Electrochemical, and Computational Aspects of the Charge Distribution in Ru(acac)2(R-o-benzoquinonediimine) Complexes
D Kalinina, C Dares, H Kaluarachchi… - Inorganic …, 2008 - ACS Publications
The syntheses and properties are reported for five Ru (acac) 2 (R-bqdi) species where acac
is acetylacetonate, and R-bqdi is the non-innocent ligand ortho-benzoquinonediimine …
is acetylacetonate, and R-bqdi is the non-innocent ligand ortho-benzoquinonediimine …
Effects of ancillary ligands on redox and chemical properties of ruthenium coordinated azoaromatic pincer
In this work, the effect of the electronically different ancillary ligands on the overall properties
of the RuIIL moiety (L= 2, 6-bis (phenylazo) pyridine) in heteroleptic complexes of general …
of the RuIIL moiety (L= 2, 6-bis (phenylazo) pyridine) in heteroleptic complexes of general …
The Semiquinone− Ruthenium Combination as a Remarkably Invariant Feature in the Redox and Substitution Series [Ru (Q) n (acac) 3− n] m, n= 1− 3; m=(− 2),− 1, 0 …
Three new compounds,[Ru (Q•−)(acac) 2]= 1,[Ru (Q•−) 2 (acac)]= 2, and [Ru (Q•−) 3]= 3,
were obtained and characterized as RuIII complexes with 4, 6-di-tert-butyl-N-phenyl-o …
were obtained and characterized as RuIII complexes with 4, 6-di-tert-butyl-N-phenyl-o …
Molecular and electronic structure of cyclo [10] thiophene in various oxidation states: polaron pair vs. bipolaron
The molecular structure of a cyclic oligothiophene, C10T, has been determined by single-
crystal X-ray structure analysis. The exclusive syn-conformation of all thiophene units as …
crystal X-ray structure analysis. The exclusive syn-conformation of all thiophene units as …
Introducing a new azoaromatic pincer ligand. Isolation and characterization of redox events in its ferrous complexes
The isolation and complete characterization of a new bis-azoaromatic ligand, 2, 6-bis
(phenylazo) pyridine (L), are described, and its coordination to iron (II) is reported. A pseudo …
(phenylazo) pyridine (L), are described, and its coordination to iron (II) is reported. A pseudo …
Photoswitchable arene ruthenium complexes containing o-sulfonamide azobenzene ligands
C Deo, N Bogliotti, R Métivier, P Retailleau… - Organometallics, 2015 - ACS Publications
A series of arene ruthenium complexes containing o-sulfonamide azobenzene ligands were
synthesized and found to exhibit uncommon coordination pattern with an exocyclic N N …
synthesized and found to exhibit uncommon coordination pattern with an exocyclic N N …
Isolation and assessment of the molecular and electronic structures of azo-anion-radical complexes of chromium and molybdenum. Experimental and theoretical …
The reaction of 3 equiv of the ligand 2-[(2-chlorophenyl) azo] pyridine (La) or 2-[(4-
chlorophenyl) azo] pyridine (Lb) with 1 equiv of Cr (CO) 6 or Mo (CO) 6 in boiling n-octane …
chlorophenyl) azo] pyridine (Lb) with 1 equiv of Cr (CO) 6 or Mo (CO) 6 in boiling n-octane …