Contemporary macrocycles for discrete polymetallic complexes: Precise control over structure and function

MT Chaudhry, S Akine, MJ MacLachlan - Chemical Society Reviews, 2021 - pubs.rsc.org
The growth of multimetallic clusters and complexes can proceed in the presence of suitable
ligands, but often leads to polydisperse structures with poor solubility. As an alternative …

Macrocyclic multinuclear metal complexes acting as catalysts for organic synthesis

BD Nath, K Takaishi, T Ema - Catalysis Science & Technology, 2020 - pubs.rsc.org
Metal clusters in nature and artificial systems are known to exhibit excellent catalytic
activities. Among various coordination systems, macrocyclic multinuclear metal complexes …

Unprecedented biological evaluation of Zn (II) complexes supported by “Self-adjustable” acyclic diiminodipyrromethane Schiff's bases: DFT, molecular docking; …

SK Loke, E Pagadala, V Srinivasadesikan… - Inorganic Chemistry …, 2021 - Elsevier
Two new self-adjustable acyclic diiminodipyrromethane Schiff's bases of composition
[(Ph)(CH 3) C (2, 6-i Pr 2 C 6 H 3-N= CH-C 4 H 2 NH) 2](L1) and [(Ph)(CH 3) C (Ph 3 CN …

Multinuclear Ni (II) and Cu (II) complexes of a meso 6+ 6 macrocyclic amine derived from trans-1, 2-diaminocyclopentane and 2, 6-diformylpyridine

J Gregoliński, K Ślepokura, J Kłak, M Witwicki - Dalton Transactions, 2022 - pubs.rsc.org
Four hexanuclear chloride and sulphate Ni (II) and Cu (II) complexes 1, 2, 4 and 5 and one
tetranuclear nitrate Cu (II) complex 3 have been synthesised from appropriate metal salts …

Polynuclear alkoxy–zinc complexes of bowl-shaped macrocycles and their use in the copolymerisation of cyclohexene oxide and CO 2

JR Pankhurst, S Paul, Y Zhu, CK Williams… - Dalton Transactions, 2019 - pubs.rsc.org
The reactions between alcohols and the tetranuclear ethyl–Zn complexes of an ortho-
phenylene-bridged polypyrrole macrocycle, Zn4Et4 (L1) 1 and the related anthracenyl …

Simple phosphinate ligands access zinc clusters identified in the synthesis of zinc oxide nanoparticles

SD Pike, ER White, MSP Shaffer… - Nature Communications, 2016 - nature.com
The bottom-up synthesis of ligand-stabilized functional nanoparticles from molecular
precursors is widely applied but is difficult to study mechanistically. Here we use 31P NMR …

A cationic tetrahedral Zn (ii) cluster based on a new salicylamide imine multidentate ligand: synthesis, structure and fluorescence sensing study

HH Meng, CY Wang, W Xi, XQ Song, L Wang - Dalton Transactions, 2019 - pubs.rsc.org
A monocationic ZnII tetrahedral cluster,[Zn4L3 (μ3-OH)]· NO3· 1.25 H2O (Zn4L3) based on a
new salicylamide imine ligand H2L, H2L= 1-(2-hydroxy-3-methoxy-benzamido)-3-(2 …

Hexa-and octanuclear copper (ii) complexes with a tetraeicosaaza amine macrocycle

D Fedorowicz, K Ślepokura, J Kłak, M Witwicki… - Dalton …, 2023 - pubs.rsc.org
One hexa-and two octanuclear Cu (II) complexes were synthesised from different metal salts
and a very large (8+ 8) tetraeicosaaza macrocycle. These nitrate, chloride and sulphate …

Unprecedented Variety of Outcomes in the Oxygenation of Dinuclear Alkylzinc Derivatives of an N,N‐Coupled Bis(β‐diketimine)

T Pietrzak, MD Korzyński, I Justyniak… - … A European Journal, 2017 - Wiley Online Library
Reactions between O2 and organometallics with non‐redox‐active metal centers have
received continuous interest for over 150 years, although significant uncertainties …

Hexanuclear and octanuclear metal complexes of octadecaazamacrocycle based on diaminocyclohexane and pyridine units

J Janczak, T Paćkowski, J Gregoliński, J Lisowski - Polyhedron, 2023 - Elsevier
An extended macrocyclic amine L derived from the [6+ 6] condensation of trans-1, 2-
diaminocyclohexane and 2, 6-diformylpyridine contains 18 nitrogen atoms in its main cycle …