Contemporary Carbocation Chemistry: Applications in Organic Synthesis | Chemical
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Abstract A selective synthesis of 5, 6‐disubstituted and 5‐substituted indazolo [2, 3‐a]
quinolines through a Rh (III)‐catalyzed oxidant‐free annulation of 2‐aryl‐2H‐indazoles with …

Friedel–Crafts Reactions with N-Heterocyclic Alcohols | The Journal of Organic Chemistry ACS
ACS Publications C&EN CAS Find my institution Log In The Journal of Organic Chemistry ACS …

Superelectrophiles are multiply charged cationic species (dications, trications, etc.) which
are characterized by their reactions with weak nucleophiles. These reactive intermediates …

The synthesis of naphthalene derivatives through three-component coupling of 2-
alkynylbenzaldehyde hydrazones with carbene complexes and electron-deficient alkynes …

Over the years, a significant number of di‐and tricationic superelectrophiles have been
studied. Many of these superelectrophiles exhibit charge–charge repulsive effects due to the …

The ability to assemble organic molecules one carbon atom at a time has been a long-held
dream for chemists. Modern boronate homologations with chiral carbenoids allow for the …

A method for visible-light-induced synthesis of polyheteroaromatics from 2-heteroaryl-
substituted anilines and heteroarylalkynes was developed. The process, which uses fac-Ir …

Silver-catalyzed tandem acetalization and cycloisomerization reactions were found to lead
to various furoquinolines, and a nitrogen effect was noticed for AgOTf reactivity, since the …

Here we report a method to reorganize the core structure of aliphatic unsaturated nitrogen‐
containing substrates exploiting polyprotonation in superacid solutions. The …