Perspective: Outstanding theoretical questions in polymer-nanoparticle hybrids

SK Kumar, V Ganesan, RA Riggleman - The Journal of chemical …, 2017 - pubs.aip.org
This topical review discusses the theoretical progress made in the field of polymer
nanocomposites, ie, hybrid materials created by mixing (typically inorganic) nanoparticles …

Physical aging in polymers and polymer nanocomposites: recent results and open questions

D Cangialosi, VM Boucher, A Alegría, J Colmenero - Soft Matter, 2013 - pubs.rsc.org
Physical aging is a ubiquitous phenomenon in glassy materials and originates from the fact
that they are generally out-of-equilibrium. Due to the technological and fundamental …

Effect of nanostructure on the thermal glass transition and physical aging in polymer materials

D Cangialosi, A Alegria, J Colmenero - Progress in Polymer Science, 2016 - Elsevier
We review the recent activity aiming to clarify glassy dynamics in nanostructured polymer
glasses, in particular thin films, nanocomposites and nanospheres. Special emphasis is …

Macromolecule and particle dynamics in confined media

CC Lin, E Parrish, RJ Composto - Macromolecules, 2016 - ACS Publications
Dynamic properties play an important role in designing functional polymer nanocomposites,
impacting molecular transport and phase separation kinetics. When nanoparticle (NP) size …

Mechanical properties and cross-link density of styrene–butadiene model composites containing fillers with bimodal particle size distribution

A Mujtaba, M Keller, S Ilisch, HJ Radusch… - …, 2012 - ACS Publications
Mechanical properties and cross-link density of model composites being solution styrene–
butadiene rubbers filled with different amounts of nanosized silica particles or mixtures of …

Microscopic dynamics of polyethylene glycol chains interacting with silica nanoparticles

T Glomann, GJ Schneider, J Allgaier, A Radulescu… - Physical review …, 2013 - APS
We present high resolution neutron spectroscopic investigations of polyethylene glycol
matrices interacting attractively with neat SiO 2 nanoparticles. We observe a very rich …

Interfacial interactions and segmental dynamics of poly (vinyl acetate)/silica nanocomposites

Y Lin, L Liu, G Xu, D Zhang, A Guan… - The Journal of Physical …, 2015 - ACS Publications
We investigate the interfacial interactions and segmental dynamics of hydrophilic and
hydrophobic (calcined) silica nanoparticle (NP) filled poly (vinyl acetate)(PVAc) composites …

Dielectric study of hydration water in silica nanoparticles

S Cerveny, GA Schwartz, J Otegui… - The Journal of …, 2012 - ACS Publications
The effect of water content on silica nanoparticles was examined by thermogravimetry
analysis (TGA), broadband dielectric spectroscopy (from 10–2 to 107 Hz), and differential …

Enthalpy recovery in nanometer to micrometer thick polystyrene films

VM Boucher, D Cangialosi, A Alegría… - Macromolecules, 2012 - ACS Publications
The physical aging of polystyrene (PS) free-standing films has been investigated as a
function of the films thickness, ranging from several micrometers to tens of nanometers. In …

AIMs: a new strategy to control physical aging and gas transport in mixed-matrix membranes

M Kitchin, J Teo, K Konstas, CH Lau… - Journal of Materials …, 2015 - pubs.rsc.org
The effect of controlling interactions between the components in a mixed-matrix membrane
at the molecular level has been explored. A systematic series of soluble metal–organic …