Resonance-stabilised hydrocarbon radicals serve as reaction intermediates in flames,
plasmas, atmospheres and interstellar space. Their stability is conferred by delocalisation of …

Aromatic radicals form in a variety of reacting gas-phase systems, where their molecular
weight growth reactions with unsaturated hydrocarbons are of considerable importance. We …

Particulate emissions generated from combustion processes of hydrocarbon fuels (soot)
have become a significant environmental issue with implications for both human health and …

Fulvenallene and fulvenallenyl are the respective C7H6 and C7H5 global minima, yet their
importance to combustion has only recently emerged. We have studied the pyrolysis of …

Abstract Isolated 2‐phenylallyl radicals (2‐PA), generated by pyrolysis from a nitrite
precursor, have been investigated by IR/UV ion dip spectroscopy using free electron laser …

The 3-ethynylcyclopentenyl radical (3ecpr) has been identified as the carrier of an electronic
spectrum with origin at 21792 cm–1 using resonant ionization and laser-induced …

Using a combination of resonant two-photon two-color ionization (R2C2PI) and laser-
induced fluorescence/dispersed fluorescence spectroscopy, we have examined the A~ 2 A …

Mass-selective two-color resonant two-photon ionization (2C-R2PI) spectra of two
resonance stabilized radicals (RSRs), 1-phenylallyl and benzylallenyl radicals, have been …

The state-dependent spectroscopy of α-methylbenzyl radical (α-MeBz) has been studied
under jet-cooled conditions. Two-color resonant two-photon ionization (2C-R2PI), laser …

The ionization energies for three resonance-stabilized radicals are determined:
cyclohexadienyl, 1-phenylpropargyl, and methylcyclohexadienyl. The recommended …