Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …
valence electron configurations have outstanding photophysical and photochemical …
Phototherapeutic anticancer strategies with first-row transition metal complexes: a critical review
Photodynamic therapy (PDT) and photoactivated chemotherapy (PACT) are therapeutic
techniques based on a photosensitizer (PS) and light. These techniques allow the spatial …
techniques based on a photosensitizer (PS) and light. These techniques allow the spatial …
Luminescent first-row transition metal complexes
C Wegeberg, OS Wenger - Jacs Au, 2021 - ACS Publications
Precious and rare elements have traditionally dominated inorganic photophysics and
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …
The great strides of iron photosensitizers for contemporary organic photoredox catalysis: On our way to the holy grail?
The scarcity of 2 nd and 3 rd row transition metals such as ruthenium, iridium, rhodium and
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …
Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel (II) Complexes
Square-planar NiII complexes and their electronically excited states play key roles in cross-
coupling catalysis and could offer new opportunities to complement well-known …
coupling catalysis and could offer new opportunities to complement well-known …
Cobalt (III) carbene complex with an electronic excited-state structure similar to cyclometalated iridium (III) compounds
Many organometallic iridium (III) complexes have photoactive excited states with mixed
metal-to-ligand and intraligand charge transfer (MLCT/ILCT) character, which form the basis …
metal-to-ligand and intraligand charge transfer (MLCT/ILCT) character, which form the basis …
A photoreactive iron (II) complex luminophore
W Leis, MA Argüello Cordero… - Journal of the …, 2022 - ACS Publications
Controlling the order and lifetimes of electronically excited states is essential to effective light-
to-potential energy conversion by molecular chromophores. This work reports a luminescent …
to-potential energy conversion by molecular chromophores. This work reports a luminescent …
Spin-flip luminescence
WR Kitzmann, J Moll, K Heinze - Photochemical & Photobiological …, 2022 - Springer
In molecular photochemistry, charge-transfer emission is well understood and widely
exploited. In contrast, luminescent metal-centered transitions only came into focus in recent …
exploited. In contrast, luminescent metal-centered transitions only came into focus in recent …
Photoactive iron complexes: more sustainable, but still a challenge
On transition metals such as iron rests lots of hope to replace precious metal catalysts in the
field of photochemistry for a more sustainable future. Indeed, significant progress has been …
field of photochemistry for a more sustainable future. Indeed, significant progress has been …
First‐Row d6 Metal Complex Enables Photon Upconversion and Initiates Blue Light‐Dependent Polymerization with Red Light
Photosensitizers for sensitized triplet‐triplet annihilation upconversion (sTTA‐UC) often rely
on precious heavy metals, whereas coordination complexes based on abundant first‐row …
on precious heavy metals, whereas coordination complexes based on abundant first‐row …