[图书][B] Organic electrochemistry

O Hammerich, B Speiser - 2016 - api.taylorfrancis.com
Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

Electronic effects of metal hexacyanoferrates: An XPS and FTIR study

SJ Gerber, E Erasmus - Materials Chemistry and Physics, 2018 - Elsevier
A series four metal hexacyanoferrates, with a general formula of K x M y [Fe (CN) 6] z· qH 2
O, with x, y, z and q representing stoichiometric numbers and M= Fe (1), Co (2), Ni (3) and …

Significance of the electron-density of molecular fragments on the properties of manganese (iii) β-diketonato complexes: an XPS and DFT study

R Gostynski, J Conradie, E Erasmus - RSC advances, 2017 - pubs.rsc.org
DFT and XPS studies were conducted on a series of nine manganese (III) complexes of the
general formula [Mn (β-diketonato) 3], with the ligand β-diketonato= dipivaloylmethanato (1) …

XPS photoelectron lines, satellite structures and Wagner plot of Cu (II) β-diketonato complexes explained in terms of its electronic environment

J Conradie, E Erasmus - Journal of Electron Spectroscopy and Related …, 2022 - Elsevier
A series of copper (II) β-diketonato complexes [Cu (R 1 CHCOCHR 2) 2], with R 1= R 2= C 6
H 5 (1); R 1= C 6 H 5 and R 2= CH 3 (2); R 1= R 2= CH 3 (3); R 1= C 6 H 5 and R 2= CF 3 …

XPS Fe 2p peaks from iron tris (β-diketonates): Electronic effect of the β-diketonato ligand

J Conradie, E Erasmus - Polyhedron, 2016 - Elsevier
The Fe 2p photoelectron lines, as measured by X-ray photoelectron spectra (XPS), of a
series of tris (β-diketonato) iron (III) complexes, are sensitive to the electron donating and …

Electrochemical and density functional theory modeled reduction of enolized 1, 3-diketones

A Kuhn, KG Von Eschwege, J Conradie - Electrochimica acta, 2011 - Elsevier
Cathodic peak potentials (E pc) of ten enolized 1, 3-substituted 1, 3-diketones, R 1 COCHC
(OH) R 2 derivatives containing electron withdrawing and/or electron donating groups, were …

A spectroscopic, electrochemical and DFT study of para-substituted ferrocene-containing chalcone derivatives: Structure of FcCOCHCH (p-tBuC6H4)

TJ Muller, J Conradie, E Erasmus - Polyhedron, 2012 - Elsevier
A comparative investigation of seven ferrocene-containing chalcones (Fc–CO–CHCH–
C6H4R, with R= OCH3, CH3, Ph, tBu, H, Br and CF3) has been performed based on their …

Properties of manganese (III) ferrocenyl-β-diketonato complexes revealed by charge transfer and multiplet splitting in the Mn 2p and Fe 2p X-ray photoelectron …

BE Buitendach, E Erasmus, JW Niemantsverdriet… - Molecules, 2016 - mdpi.com
A series of ferrocenyl-functionalized β-diketonato manganese (III) complexes,[Mn
(FcCOCHCOR) 3] with R= CF3, CH3, Ph (phenyl) and Fc (ferrocenyl) was subjected to a …

Consequences of electron-density manipulations on the X-ray photoelectron spectroscopic properties of ferrocenyl-β-diketonato complexes of manganese (III) …

BE Buitendach, E Erasmus, M Landman… - Inorganic …, 2016 - ACS Publications
Reaction of [Mn3 (OAc) 6O· 3H2O]+(1) with ferrocenyl β-diketones of the type
FcCOCH2COR with R= CF3 (2a) and CH3 (2b), Ph= C6H5 (2c), and Fc= FeII (η5-C5H4)(η5 …

X-ray photoelectron spectroscopy: Charge transfer in Fe 2p peaks and inner-sphere reorganization of ferrocenyl-containing chalcones

E Erasmus - Journal of Electron Spectroscopy and Related …, 2018 - Elsevier
A systematic analysis of the XPS Fe 2p 3/2 core-level photoelectron lines and their satellite
structures gave insight into the electronic properties of a series of ferrocenyl-containing …