[图书][B] Electroanalytical Chemistry: A Series of Advances: Volume 23

AJ Bard, CG Zoski - 2010 - taylorfrancis.com
Electroanalytical chemists and others are concerned not only with the application of new
and classical techniques to analytical problems, but also with the fundamental theoretical …

Determining the Gibbs Energy of Ion Transfer Across Water–Organic Liquid Interfaces with Three‐Phase Electrodes

F Scholz, R Gulaboski - ChemPhysChem, 2005 - Wiley Online Library
Ions can be transferred between immiscible liquid phases across a common interface, with
the help of a three‐electrode potentiostat, when one phase is an organic droplet attached to …

[图书][B] Electrochemistry of immobilized particles and droplets

F Scholz, U Schröder, R Gulaboski… - 2005 - Springer
Fundamental Electrode Kinetics is represented by treatments of reactions such as O2+ 4H++
4e À Æ 2H2O, still important in the theory of electrocatalysis. As for the cutting edge in …

Equations for the transfer of neutral molecules and ionic species from water to organic phases

MH Abraham, WE Acree Jr - The Journal of Organic Chemistry, 2010 - ACS Publications
Equations that can be used for partition coefficients of both neutral molecules and ions have
been revised, and the term that is specific to ions has been re-evaluated. A new method has …

The effect of alcohols as vehicles on the percutaneous absorption and skin retention of ibuprofen modified with l-valine alkyl esters

P Ossowicz, J Klebeko, E Janus, A Nowak… - RSC …, 2020 - pubs.rsc.org
The effect of various alcohols as vehicles on skin permeability was compared for unmodified
ibuprofen (IBU) and ion pairs of ibuprofen with L-valine alkyl esters [ValOR][IBU], in which …

Polymeric nanoparticles–Influence of the glass transition temperature on drug release

S Lappe, D Mulac, K Langer - International journal of pharmaceutics, 2017 - Elsevier
The physico-chemical characterisation of nanoparticles is often lacking the determination of
the glass transition temperature, a well-known parameter for the pure polymer carrier. In the …

Descriptors for ions and ion-pairs for use in linear free energy relationships

MH Abraham, WE Acree Jr - Journal of Chromatography A, 2016 - Elsevier
The determination of Abraham descriptors for single ions is reviewed, and equations are
given for the partition of single ions from water to a number of solvents. These ions include …

The determination of the standard Gibbs energies of ion transfer between water and heavy water by using the three-phase electrode approach

R Gulaboski, K Caban, Z Stojek, F Scholz - Electrochemistry …, 2004 - Elsevier
For the first time, the standard Gibbs energies of transfer of anions and cations across the
nitrobenzene| heavy water interface are reported as measured by an electrochemical …

Gibbs energies of transfer of chiral anions across the interface water| chiral organic solvent determined with the help of three-phase electrodes

F Scholz, R Gulaboski - Faraday Discussions, 2005 - pubs.rsc.org
For the first time the differences in free energies have been experimentally determined for
the solvation of two enantiomeric ions in two enantiomeric solvents. Three-phase electrodes …

The transfer of neutral molecules, ions and ionic species from water to wet octanol

MH Abraham, WE Acree Jr - Physical Chemistry Chemical Physics, 2010 - pubs.rsc.org
Partition coefficients for transfer from water to wet octanol have been set out for permanent
ions, and for ionic species derived from neutral molecules by loss or acceptance of a proton …