1. History 3422. Activation barriers 3432.1 Redox potentials 3442.2 Reorganization energy
3443. Electronic coupling 3454. Ru-modified proteins 3484.1 Reorganization energy …

Electron transfers in photosynthesis and respiration commonly occur between metal-
containing cofactors that are separated by large molecular distances. Understanding the …

Recent investigations have shed much light on the nuclear and electronic factors that control
the rates of long-range electron tunneling through molecules in aqueous and organic …

Rates of reduction of Os (III), Ru (III), and Re (I)* by Cu (I) in His83-modified Pseudomonas
aeruginosa azurins (M− Cu distance∼ 17 Å) have been measured in single crystals, where …

Nanoparticle/nanowire assemblies with a degree of radial organization were prepared
around luminescent semiconducting CdTe nanowires using bioconjugation with streptavidin …

The current understanding of electron tunneling through proteins has come from work on
systems where donors and acceptors are held at fixed distances and orientations. The …

We present a broad study of the effect of neutralizing the two negative charges of the Mb
propionates on the interaction and electron transfer (ET) between horse Mb and bovine cyt b …

X-ray crystallography provides structural details of biological macromolecules. Whereas
routine data are collected close to 100 K in order to mitigate radiation damage, more exotic …

Long-range electronic interactions between electron donors and acceptors in proteins
depend on the structure of the intervening polypeptide. Several methods have been …

The nature of the dynamical coupling between a protein and its surrounding solvent is an
important, yet open issue. Here we used temperature‐dependent protein crystallography to …